Abstract
Since the 1980s there has been a significant lowering of the platinum loading of polymer electrolyte fuel cell electrodes from about 4–10 mg cm−2(platinum black) to about 0.4 mg cm−2 or even less (carbon supported platinum), by the introduction of ionomer (liquid Nafion®) impregnated gas diffusion electrodes, extending the three-dimensional reaction zone. From the 1990s to the present studies have been carried out to decrease the loss of performance during cell operation due both to the presence of liquid water causing flooding of the catalyst layer and mass transport limitations and to the poisoning of platinum by the use of reformed fuels. This review deals with the developments in electrode configuration going from dual layer to three layer electrodes. The preparation methods, the characteristics and the optimal composition of both diffusion and reactive layers of these electrodes are described. The improvement in the performance of both CO tolerant anodes and cathodes with enhanced oxygen reduction by Pt alloying is also discussed.
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References
P. Costamagna and S. Srinivasan, J. Power Sources 102 (2001) 242.
P. Costamagna and S. Srinivasan, J. Power Sources 102 (2001) 253.
I. D. Raistrick, in J.W. Van Zee, R.E. White, K. Kinoshita and H.S. Burney (Eds), Proceedings of the Symposium on ‘Diaphragms, Separators and Ion Exchange Membranes’, The Electrochemical Society, Pennington, NJ (1986), p. 172.
S. Srinivasan, E.A. Ticianelli, C.R. Derouin and A. Redondo, J. Power Sources 22 (1988) 359.
E.A. Ticianelli, C.R. Derouin, A. Redondo and S. Srinivasan, J. Electrochem. Soc. 135 (1988) 2209.
D. Bevers, M. Wohr, K. Yasuda and K. Oguro, J. Appl. Electrochem. 27 (1997) 1254.
D.M. Bernardi and M.W. Verbrugge, J. Electrochem. Soc. 139 (1992) 2477.
E. Passalacqua, F. Lufrano, G. Squadrito, A. Patti and L. Giorgi, Electrochim. Acta 43 (1998) 3665.
J-M. Song, S-Y. Cha and W-M. Lee, J. Power Sources 94 (2001) 78.
Z. Qi and A. Kaufman, J. Power Sources 109 (2002) 38.
E. Passalacqua, F. Lufrano, G. Squadrito and A. Patti, in ‘Development of Low Pt Loading Electrodes’, external report (CNR Messina, June 1996).
Z. Poltarzewski, P. Staiti, V. Alderucci, G. Maggio, N. Giordano and A. Fasulo, J. Appl. Electrochem. 22 (1992) 663.
P. Staiti, Z. Poltarewski, V. Alderucci and N. Giordano, Int. J. Hydrogen Energy 19 (1994) 254.
M. Uchida, Y. Aoyama, M. Tanabe, N. Yanagihara, N. Eda and A. Ohta, J. Electrochem. Soc. 142 (1995) 2572.
M. Watanabe, M. Tomokawa and S. Motoo, J. Electroanal. Chem. 195 (1985) 81.
N. Giordano, E. Passalacqua, V. Alderucci, P. Staiti, L. Pino, H. Mirzaian, E.J. Taylor and G. Wilemski, Electrochim. Acta 36 (1991) 1049.
T. Maoka, Electrochim. Acta 33 (1988) 379.
J.H. Nam and M. Kaviany, submitted to Int. J. Heat Mass Transf.
X. Cheng, B. Yi, M. Han, J. Zhang, Y. Qiao and J. Yu, J. Power Sources 79 (1999) 75.
A.S. Aricò, V. Antonucci, V. Alderucci, E. Modica and N. Giordano, J. Appl. Electrochem. 23 (1993) 1107.
M. Uchida, Y. Aoyama, N. Eda and A. Ohta, J. Electrochem. Soc. 142 (1995) 4143.
S.J. Lee, S. Mukerjee, J. McBreen, Y.W. Rho, Y.T. Kho and T.H. Lee, Electrochim. Acta 43 (1998) 3693.
Z. Poltarewski, P. Staiti, V. Alderucci, W. Wieczarek and N. Giordano, J. Electrochem. Soc. 139 (1992) 761.
Y-S. Hsu, C-S. Hsu and Y-C. Cheng, in Proceedings of the 3rd International Fuel Cell Conference. Nagoya, Japan (1999), p. 503.
E. Antolini, A. Pozio, L. Giorgi and E. Passalacqua, J. Mater. Sci. 33 (1998) 1837.
L. Giorgi, E. Antolini, A. Pozio and E. Passalacqua, Electrochim. Acta 43 (1998) 3675.
Y.W. Rho and S. Srinivasan, J. Electrochem. Soc. 141 (1994) 2089.
H-S. Chu, C. Yeh and F. Chen, J. Power Sources, in press.
F. Lufrano, E. Passalacqua, G. Squadrito, A. Patti and L. Giorgi, J. Appl. Electrochem. 29 (1999) 445.
E. Passalacqua, G. Squadrito, F. Lufrano, A. Patti and L. Giorgi, J. Appl. Electrochem. 31 (2001) 449.
M. Neergat and A.K. Shukla, J. Power Sources 104 (2002) 289.
C-S. Kong, D-Y. Kim, H-K. Lee, Y-G. Shul and T-H. Lee, J. Power Sources 108 (2002) 185.
L.R. Jordan, A.K. Shukla, T. Behrsing, N.R. Avery, B.C. Muddle and M. Forsyth, J. Appl. Electrochem. 30 (2000) 641.
L.R. Jordan, A.K. Shukla, T, Behrsing, N.R. Avery, B.C. Muddle and M. Forsyth, J. Power Sources 86 (2000) 250.
J. Moreira, A.L. Ocampo, P.J. Sebastian, M.A. Smit, M.D. Salazar, P. del Angel, J.A. Montoya, R. Perez and L. Martinez, Int. J. Hydrogen Energy 28 (2003) 625.
S. Besse, G. Bronoel and J.F. Fauvarque, in ‘Resumé des Journeés d'Etude Piles à Combustible’. (Paris, 1999) p. 2102.
Z. Qi and A. Kaufman, J. Power Sources 113 (2003) 37.
E. Antolini, L. Giorgi, A. Pozio and E. Passalacqua, J. Power Sources 77 (1999) 136.
M.S. Wilson and S. Gottesfeld, J. Appl. Electrochem. 22 (1992) 1.
M.S. Wilson and S. Gottesfeld, J. Electrochem. Soc. 139 (1992) L28.
E. Passalacqua, F. Lufrano, G. Squadrito, A. Patti and L. Giorgi, Electrochim. Acta 46 (2001) 799.
V.A. Paganin, E.A. Ticianelli and E.R. Gonzalez, J. Appl. Electrochem. 26 (1996) 297.
Y-G. Yoon, G-G. Park, T-H. Yang, J-N. Han, W-Y. Lee and C-S. Kim, Int. J. Hydrogen Energy 28 (2003) 657.
E. Antolini, R.R. Passos and E.A. Ticianelli, J. Appl. Electrochem. 32 (2002) 383.
E. Antolini, R.R. Passos and E.A. Ticianelli, J. Power Sources 109 (2002) 477.
E.J. Taylor, E.B. Anderson and N.R.K. Vilambi, J. Electrochem. Soc. 139 (1992) L45.
G.S. Kumar, M. Raja and S. Parthasarathy, Electrochim. Acta 40 (1995) 285.
M.S. Wilson, J.A. Valerio and S. Gottesfeld, Electrochim. Acta 40 (1995) 355.
Y.G. Chun, C.S. Kim, D.H. Peck and D.R. Shin, J. Power Sources 71 (1998) 174.
Z. Qi and A. Kaufman, J. Power Sources 113 (2003) 115.
H.F. Oetjen, V.M. Schmidt, U. Stimming and F. Trila, J. Electrochem. Soc. 143 (1996) 3838.
A. Kabbabi, R. Faure, R. Durand, B. Beden, F. Hahn, J.M. Leger and C. Lamy, J. Electroanal. Chem. 444 (1998) 41.
H.A. Gasteiger, N.M. Markovic, P.N. Ross and E.J. Cairns, J. Phys. Chem. 98 (1994) 617.
V.M. Schmidt, R. Ianniello, H.F. Oetjen and H. Reger, in S. Gottesfeld, G. Halpert and A. Landgrebe (Eds), ‘Proton Conducting Membrane Fuel Cells I‘, The Electrochemical Society Proceedings Series. Pennington, NJ (1995), p.1.
T. Iwasita, R. Dalbeck, E. Pastor and X. Xia, Electrochim. Acta 11/12 (1994) 1817.
H.A. Gasteiger, N.M. Markovic, P.N. Ross and E.J. Cairns, Electrochim. Acta 11/12 (1994) 1825.
R. Ianniello, V.M. Schmidt, U. Stimming, J. Stumper and A. Wallau, Electrochim. Acta 11/12 (1994) 1863.
P. Wolohan, P.C.H. Mitchell, D. Thompsett and S.J. Cooper, J. Mol. Catal. A 119 (1997) 223.
A. Pozio, L. Giorgi, E. Antolini and E. Passalacqua, Electrochim. Acta 46 (2000) 555.
M. Watanabe and S. Motoo, J. Electroanal. Chem. 60 (1975) 275.
M. Krauza and W. Vielstich, J. Electroanal. Chem. 379 (1994) 307.
T. Iwasita, F.C. Nart and W. Vielstich, Ber. Bunsengen. Phys. Chem. 94 (1990) 1030.
J.B. Goodenough, R. Manoharan, A.K. Shukla and K.V. Ramesh, Chem. Mater. 1 (1989) 391.
J. McBreen and S. Mukerjee, J. Electrochem. Soc. 142 (1995) 3399.
H. Igarashi, T. Fujino, Y. Zhu, H. Uchida and M. Watanabe, Phys. Chem. Chem. Phys. 3 (2001) 306.
S.J. Lee, S. Mukerjee, E.A. Ticianelli and J. McBreen, Electrochim. Acta 44 (1999) 3283.
E. Antolini, L. Giorgi, F. Cardellini and E. Passalacqua, J. Solid State Electrochem. 5 (2001) 131.
G.A. Camara, M.J. Giz, V.A. Paganin and E.A. Ticianelli, J. Electroanal. Chem. 537 (2002) 21.
E. Antolini, Mater. Chem. Phys. 78 (2003) 563.
P. Gouérec, M.C. Denis, D. Guay, J.P. Dodelet and R. Schulz, J. Electrochem. Soc. 147 (2000) 3989.
B.N. Grgur, N.M. Markovic and P.N. Ross, J. Electrochem. Soc. 146 (1999) 1613.
S. Mukerjee, S.J. Lee, E.A. Ticianelli, J. McBreen, B.N. Grgur, N.M. Markovic, P.N. Ross, J.R. Giallombardo and E.S. De Castro, Electrochem. Solid State Lett. 2 (1999) 12.
P.N. Ross, K. Kinoshita, A.J. Scarpellino and P. Stonehart, J. Electroanal. Chem. 63 (1975) 97.
A. Gamez, D. Richard and P. Gallezot, in ‘Resumé des Journeés d'Etude Piles à Combustible’ (Paris, 1999), p. 401.
K.V. Ramesh, P.R. Sarode, S. Vasudevan and A.K. Shukla, J. Electroanal. Chem. 223 (1987) 91.
S. Mukerjee, J. Appl. Electrochem. 23 (1990) 537.
S. Mukerjee and S. Srinivasan, J. Electroanal. Chem. 357 (1993) 201.
S. Mukerjee, S. Srinivasan, M.P. Soriaga and J. McBreen, J. Electrochem. Soc. 142 (1995) 1409.
V.A. Paganin, PhD thesis, S. Paulo, Brazil (1996).
E. Antolini, R.R. Passos and E.A. Ticianelli, Electrochim. Acta 48 (2002) 263.
J. Shim, C-R. Lee, H-K. Lee, J.S. Lee and E.J. Cairns, J. Power Sources 102 (2001) 172.
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Antolini, E. Review in Applied Electrochemistry. Number 54 Recent Developments in Polymer Electrolyte Fuel Cell Electrodes. Journal of Applied Electrochemistry 34, 563–576 (2004). https://doi.org/10.1023/B:JACH.0000021923.67264.bb
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DOI: https://doi.org/10.1023/B:JACH.0000021923.67264.bb