Abstract
Ammonia-treated activated carbon has been studied as a support of Ru-Ba catalyst for ammonia synthesis. It is shown that the introduction of nitrogen leads to a decrease of ammonia synthesis activity for the catalysts with a low Ba/Ru molar ratio, while no significant changes are obtained for the catalysts with a high Ba/Ru molar ratio, confirming that electronegative impurities suppress the activity in ammonia synthesis and consume part of the promoters.
Similar content being viewed by others
REFERENCES
L.R. Radovic, F. Rodriguez-Reinoso: in Chemistry and Physics of Carbon (A. Thrower, Ed), Vol.25, p. 243. Marcel Dekker, New York 1997.
H.P. Boehm: Carbon, 32, 759 (1994).
B. Stohr, H.P. Boehm, R. Schlogl: Carbon, 29, 707 (1991).
H.P. Boehm, G. Mair, T. Stoehr, A.R. de Rincon, B. Tereczki: Fuel, 63, 1061 (1984).
F.J. Derbyshire, V.H.J. de Beer, G.M.K. Abotsi, A.W. Scaroni, J.M. Solar, D.J. Skrovanek: Appl. Catal., 27, 117 (1986).
F.P. Daly, J.S. Brinen: Appl. Catal., 30, 91 (1987).
A. Guerrero-Ruiz, I. Rodriguez-Ramos, F. Rodriguez-Reinoso, C. Moreno-Castilla, J.D. Lopez-Gonzalez: Carbon, 26, 417 (1988).
F. Xie, J. Phillips, I.F. Silva, M.C. Palma, J.A. Menendez: Carbon, 38, 691 (2000).
G.M.K. Abotsi, A.W. Scaroni: Carbon, 28, 79 (1990).
P. Vinke, M. Van der Euk, M. Verbree, A.F. Voskamp, H. Van Bekkum: Carbon, 32, 675 (1994).
K. Aika, K. Tamaru: in Ammonia, Catalysis and Manufacture (A. Nielson, Ed), p. 103. Springer-Verlag, Berlin 1995.
J.R. Jennings: Catalytic Ammonia Synthesis. Plenum Press, New York 1991.
Z. Zhong, K. Aika: Chem. Commun., 1223 (1997).
L.Y. Leon, C.A. Solar, J.M. Calemma, L.R. Radovic: Carbon, 30, 797 (1992).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Liang, C., Wei, Z., Xin, Q. et al. Ammonia-treated activated carbon as support of Ru-Ba catalyst for ammonia synthesis. Reaction Kinetics and Catalysis Letters 83, 39–45 (2004). https://doi.org/10.1023/B:REAC.0000037374.92480.f1
Issue Date:
DOI: https://doi.org/10.1023/B:REAC.0000037374.92480.f1