Abstract
Alkyl glycosides were used as templating surfactants in the sol–gel processing of thin silica films. The sols were made from a prehydrolyzed silicate solution with the addition of a glucoside or a maltoside surfactant. The sol–gel–xerogel transitions and the silica–sugar interactions were studied by IR ATR spectroscopy. The siloxane condensation rate in the silica/glycoside sol was considerably reduced compared to a pure silica system due to hydrogen bonding interactions between the silanols and the sugar head groups. Thin films were deposited on silicon wafers and characterized by IR transmission, X-ray diffraction and TEM analysis. The size of the sugar head group had a large influence on the type of the mesophases formed. The use of the glucoside surfactant only resulted in temperature unstable lamellar phases, whereas the maltosides at low concentrations assembled in curved mesophases that were stable to template removal by extraction or calcination.
Similar content being viewed by others
References
Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartulli, J.C. & Beck, J.S. 1992 Nature 359, 710.
Edler, K.J. & Roser, S.J. 2001 Int. Rev. Phys. Chem. 20, 387.
Lu, Y., Ganguli, R., Drewien, C.A., Anderson, M.T., Brinker, C.J., Gong, W.L., Guo, Y.X., Soyez, H., Dunn, B., Huang, M.H. & Zink, J.I. 1997 Nature 398, 364.
Grosso, D., Babonneau, F., Albouy, P.-A., Amenitsch, H., Balke-nende, A.R., Brunet-Bruneau, A. & Rivory, J. 2002 Chem. Mater. 14, 931.
Nilsson, F. & S¨ oderman, O. 1996 Langmuir 12, 902.
Sakya, P., Seddon, J.M. & Vill, V. 1997 Liq. Cryst. 23, 409.
Boyd, B.J., Drummond, C.J., Krodkiewska, I. & Grieser, F. 2000 Langmuir 16, 7359.
von Minden, H.M., Brandenburg, K., Seydel, U., Koch, M.H.J., Garamus, V., Willumeit, R. & Vill, V. 2000 Chem. Phys. Lipids 106, 157.
Innocenzi, P., Falcaro, P., Grosso, D. & Babonneau, F. 2002 Mat. Res. Soc. Symp. Proc. 726, 271.
Clark, T. Jr., Ruiz, J.D., Fan, H., Brinker, C.J., Swanson, B.I. & Parikh, A.N. 2000 Chem. Mater. 12, 3879.
Yu, S., Wong, T.K.S., Pita, K. & Hu, X. 2002 J. Vac. Sci. Technol. B 20, 2036.
Hua, Z.-L., Shi, J.-L., Wang, L. & Zhang, W.-H. 2001 J. Non-Cryst. Solids 292, 177.
Berquier, J.-M., Nael, P., Jupille, J. & Jacquiod, C. 2000 J. Sol-Gel Sci. Technol. 19, 83.
Lavrenčič-Štangar, U., Orel, B., Neumann, B., Stathatos, E. & Lianos, P. 2003 J. Sol-Gel Sci. Technol. 26, 1113.
Wei, Y. Xu, J., Dong, H., Dong, J.H., Qiu, K. & Jansen-Varnum S.A. 1999 Chem. Mater. 11, 2023.
Zhang, L., Somasundaran, P. & Maltesh, C. 1997 J. Colloid Interface Sci. 191, 202.
Jung, J.H., Amaike, M., Nakashima, K. & Shinkai, S. 2001 J. Chem. Soc. Perkin Trans. 2, 1938.
Lavrenčič-Štangar, U., Puchberger, M. & H¨ using, N. 2002 Mat. Res. Soc. Symp. Proc. 726, 111.
Minden, H.M., Brandenburg, K., Seydel, U., Koch, M.H.J., Garamus, V., Willumeit, R. & Vill, V. 2000 Chem. Phys. Lipids 106, 157.
Gnado, J., Dhamelincourt, P., P´ el´ egris, C., Traisnel, M. & Le Maguer Mayot, A. 1996 J. Non-Cryst. Solids 208, 247.
Kung, K.-H.S. & Hayes, K.F. 1993 Langmuir 9, 263.
Kačur´akov´a M. & Mathlouthi, M. 1996 Carbohydr. Res. 284, 145.
Sekkal, M., Dincq, V., Legrand, P. & Huvenne, J.P. 1995 J. Mol. Struct. 349, 349.
Almeida, R.M. & Pantano, C.G. 1990 J. Appl. Phys. 68, 4225.
Crepaldi, E.L., Soler-Illia, G.J. de A.A., Grosso, D., Sanchez, C. & Albouy, P.-A. 2001 Chem. Commun. 17, 1582.
Israelachvili, J.N. 1998 Intermolecular and Surface Forces, 2nd ed., p. 36. San Diego, California: Academic Press Inc.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Štangar, U.L., Hüsing, N. Alkyl-glycoside surfactants in the synthesis of mesoporous silica films. Silicon Chemistry 2, 157–165 (2003). https://doi.org/10.1023/B:SILC.0000046724.80191.21
Issue Date:
DOI: https://doi.org/10.1023/B:SILC.0000046724.80191.21