Skip to main content
Log in

Silicon Carbide: A Novel Catalyst Support for Heterogeneous Catalysis

  • Published:
CATTECH

Abstract

Progress in developing a new class of support materials based on silicon carbide (SiC)is reviewed. Silicon carbide has superior mechanical and thermal properties which, coupled to chemical inertness,avoids several of the problems inherent in the use of commercial oxide and carbon based supports and catalysts. High surface area SiC can now be prepared easily in a commercially viable shape,with good mechanical properties,and at reasonable cost.I t can be shaped directly into monolith or honeycomb forms including some catalytically active material, rendering fabrication simple and cost effective. Furthermore, it can be modified for specific catalytic applications through the addition of metals. In many respects, it combines the best properties of oxide and carbon based supports without suffering many of their disadvantages.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

references

  1. J. A. Schwarz, C. Contescu, and A. Contescu, Chem. Rev., 95 (1995) 477.

    Google Scholar 

  2. H. C. Yao, H. K. Stepien, H. S. Gandhi, J. Catal., 61 (1980) 547.

    Google Scholar 

  3. H. J. Sanders, Chem. Eng. News, 62 (1984) 26.

    Google Scholar 

  4. A. Addamino and J. A. Sprague, Appl. Phys. Lett., 44 (1984) 525.

    Google Scholar 

  5. R. Marchand, Y. Laurent, J. Guyader, P. L'Haridon, and P. Verdier, J. Eur. Ceram. Soc., 8 (1991) 197.

    Google Scholar 

  6. G.C.T. Wei, J. Am. Ceram. Soc., 66 (1983) C111.

    Google Scholar 

  7. J. R.Fox, D. A. White, S. M. Oleff, R. D. Boyer, and P. A. Budinger, Mater. Res. Soc. Symp. Proc., 73 (1986) 395.

    Google Scholar 

  8. P. W. Lednor and R. de Ruiter, J. Chem. Soc., Chem. Commun., (1989) 320.

  9. P. W. Lednor and R. de Ruiter, J. Chem. Soc., Chem. Commun., (1991) 1625.

  10. K. P. Triplett, J. H. Burk, F. G. Sherif, and W. Vrengdenhil, Akzo Nobel Co., US Patent No. 5,338,716, 1994.

  11. F. G. Sherif and W. Vrengdenhil, in “The Chemistry of Transition Metal Carbides and Nitrides”, S. T. Oyama, Ed., Chapman and Hall, 1996, pp. 414.

  12. R. W. Chorley and P. W. Lednor, 3(1991) 474.

  13. C. E. Ryan, I. Berman, R. C. Marshall, D. P. Considine and J. J. Hawley, J. Crys. Growth, 1 (1967) 255.

    Google Scholar 

  14. S. K. Varshney and C. L. Beatty, Ceram. Eng. Sci. Proc., 3 (1982) 555.

    Google Scholar 

  15. Y. Okabe, J. Hojo and A. Kato, J. Less-Common Metals, 68 (1979) 29.

    Google Scholar 

  16. R. Moene, M. Makkee, and J. A. Moulijn, Applied Catal. A: General 167 (1998) 321.

    Google Scholar 

  17. R. Moene, E. P. Tijser, M. Makkee and J. A. Moulijn, Applied Catal. A: General 184 (1998) 127.

    Google Scholar 

  18. N. M. Rodriguez, J. Mater. Res., 8 (1993) 3233.

    Google Scholar 

  19. O. Yamada, Y. Miyamoto, and M. Koizumi, Bull. Am. Ceram. Soc., 64 (1985) 319.

    Google Scholar 

  20. O. Yamada, Y. Miyamoto, and M. Koizumi, J. Mater. Res., 1 (1986) 275.

    Google Scholar 

  21. R. Pampuch, L. Stobierski, J. Lis and M. Racka, Mater. Res. Bull., 22 (1987) 1225.

    Google Scholar 

  22. P. W. Lednor, Catal. Today, 15 (1992) 243.

    Google Scholar 

  23. M. A. Vannice, Y. L. Chao, and R. M. Friedman, Appl. Catal., 20 (1986) 91.

    Google Scholar 

  24. C. M. Hollabaugh, D. E. Hull, L. R. Newkirk, and J. J. Petrovic, J. Mater. Sci., 18 (1983) 3190.

    Google Scholar 

  25. C. W. Zhu, G. Y. Zhao, V. Revankar, and V. Hlavacek, J. Mater. Sci., 28 (1993) 659.

    Google Scholar 

  26. M. J. Ledoux, J. Guille, S. Hantzer, and D. Dubots, U.S. Pat. No. 4,914,070, 1990; M. J. Ledoux, S. Hantzer, C. Pham-Huu, J. Guille, and M. P. Desaneaux, J. Catal., 114 (1988) 176.

  27. N. Keller, C. Pham-Huu, S. Roy, M. J. Ledoux, C. Estournes, J. Guille, J. Mat. Sci., 34 (1999) 3189.

    Google Scholar 

  28. M. J. Ledoux and C. Pham-Huu, Catal. Today, 15 (1992) 263.

    Google Scholar 

  29. P. Kennedy and B. North, Proc. Brit. Ceram. Soc., 33 (1983) 1.

    Google Scholar 

  30. M. Benaissa, J. Werckmann, J. L. Hutchison, E. Peschiera, J. Guille, and M. J. Ledoux, J. Crys. Growth, 131 (1993) 5.

    Google Scholar 

  31. M. N. Rahaman and L. C. De Jonghe, Am. Cream. Soc. Bull., 66 (1987) 782.

    Google Scholar 

  32. J. Zhu, X. G. Ning, H. G.Xu, K. Y. Hu, W. Cao, and H. Q. Ye, J. Mater. Sci., 26 (1991) 3202.

    Google Scholar 

  33. J. Lipowitz, H. A. Freeman, R. T. Chen, and E. R. Prack, Adv. Ceram. Mater., 2 (1987) 121.

    Google Scholar 

  34. C. Laffon, A. M. Flank, R. Hagege, P. Orly, J. Cotteret, M. Laridjani, J. Dixmier, J. L. Miquel, H. Hommel, and A. P. Legrand, J. Mater. Sci., 24 (1989) 1503.

    Google Scholar 

  35. A. Julbe, A. Larbot, C. Guizard, L. Cot, T. Dupin, J. Charpin, and P. Bergez, Eur. J. Solid State Inorg. Chem. 26 (1989) 101.

    Google Scholar 

  36. G. M. Renlund, S. Prochazka, and R. H. Doremus, J. Mater. Res. 6 (1991) 2716 & 2723.

    Google Scholar 

  37. N. Mozdzierz, M. Backhaus-Ricoult, and D. Imhoff, Proc.13 Inter. Congr. Electron Micros., Les Editions de Physiques, B. Jouffrey and C. Colliex, Eds., 2A, 251, 1993.

  38. M. Prin, B. Ollivier, and P. Lamaze, U.S. Pat. Appl. 08/955093 (1995).

    Google Scholar 

  39. G. Baluais and B. Ollivier, PCT WO 98/30328 (1998).

  40. M. Prin and B. Ollivier, PCT WO 99/04900 (1999).

  41. S. Marin, PhD Dissertation, University of Strasbourg, France, 1991.

  42. C. Pham-Huu, S. Marin, M. J. Ledoux, M. Weibel, G. Ehret, M. Benaissa, E. Peschiera, and J. Guille, Appl. Catal. B, Environ., 4 (1994) 45.

    Google Scholar 

  43. C. Pham-Huu, C. Bouchy, T. Dintzer, G. Ehret, C. Estournes, and M. J. Ledoux, Appl. Catal. A, 180 (1999) 385.

    Google Scholar 

  44. M. J. Ledoux, J. Guille, C. Pham-Huu and S. Marin, U.S. Pat. No. 5,308,597 (1994) and U.S. Pat. No. 5,391,524 (1995).

  45. F. Meunier, P. Delporte, B. Heinrich, C. Bouchy, C. Crouzet, C. Pham-Huu, P. Panissod, J. J. Lerou, P. L. Mills, and M. J. Ledoux, J. Catal., 169 (1997) 33.

    Google Scholar 

  46. M. J. Ledoux, N. Keller, C. Pham-Huu, C. Estournes, B. Heinrich, H. Lamprell, and E. M. Harlin, in Preparation of Catal. VII, Louvain, B. Delmon et al., Eds., Elsevier, 1998, p. 855.

  47. C. Pham-Huu, M. J. Ledoux, and J. Guille, J. Catal., 143 (1993) 249.

    Google Scholar 

  48. E. A. Blekkan, C. Pham-Huu, M. J. Ledoux, and J. Guille, Ind. Eng. Chem. Res., 33 (1994) 1657.

    Google Scholar 

  49. M. J. Ledoux, J. Guille, C. Pham-Huu, E. A. Blekkan and E. Peschiera, Eur. Pat. Appl. No. 93-14199.

  50. C. Pham-Huu, P. Del Gallo, E. Peschiera, and M. J. Ledoux, Appl. Catal. A: General, 132 (1995) 77.

    Google Scholar 

  51. M. J. Ledoux, P. Del Gallo, C. Pham-Huu and A. P. E. York, Catal. Today, 27 (1996) 145.

    Google Scholar 

  52. A. O. I. Krause, M. J. Ledoux, F. Meunier, P. Del Gallo, C. Pham-Huu, V. Niemi, and J. Hiltunen, Finish Pat. Appl. No. 95-0751 (1995).

  53. M. E. Harlin, A. O. I. Krause, B. Heinrich, C. Pham-Huu, and M. J. Ledoux, Appl. Catal. A: General, 185 (1999) 311.

    Google Scholar 

  54. P. H. Berben and J. W. Geus, U.S. Patent No. 4,818,740 (1989).

  55. M. J. Ledoux, J.-B. Nougayrède, C. Pham-Huu, N. Keller, S. Savin-Poncet, C. Crouzet, French Pat. Appl. No. 98-1 1941 (1998).

  56. S. Savin, J.-B. Nougayrède, W. Willing, and G. Bandel, New Developments in Sulfur Recovery Process Technology, in The International Journal of Hydrocarbon Engineering, 54 (1998) 1.

    Google Scholar 

  57. M. J. Ledoux, J. B. Nougayrède, C. Pham-Huu, N. Keller, S. Savin-Poncet, and C. Crouzet, French Pat. Appl. No. 98-1 1941 (1998).

  58. M. J. Ledoux, C. Pham-Huu, N. Keller, J. B. Nougayrède, S. Savin-Poncet, W. Boll, R. Morgenroth, Sulfur, 269 (2000) 41.

    Google Scholar 

  59. P. H. Berben, PhD Dissertation, University of Utrecht, The Netherlands, 1985.

  60. J. T. Wrobleski, J. W. Edwards, C. R. Graham, R. A. Keppel, and M. Raffelson, U.S. Pat. No. 4,562,268 (1985).

  61. R. M. Contractor, H. E. Bergna, H. S. Horowitz, C. M. Blackstone, B. Malone, C. C. Torardi, B. Griffiths, U. Chowdhry, and A. W. Sleight, Catal. Today, 1 (1987) 49.

    Google Scholar 

  62. M. J. Ledoux, C. Crouzet, C. Bouchy, B. Heinrich, K. Kourtakis, P.L. Mills, J. J. Lerou, U.S. Pat. Appl. No. CL-1097-P1 (1998).

  63. M. Funabiki, T. Yamada, and K. Kayano, Catal. Today, 10 (1991) 33.

    Google Scholar 

  64. T. Wang and L. D. Schmidt, J. Catal., 70 (1981) 187.

    Google Scholar 

  65. M. J. Ledoux, C. Pham-Huu, S. Marin, M. Weibel, and J. Guille, C.R. Acad. Sci. Paris, 310, Série II (1990) 707.

    Google Scholar 

  66. C. Pham-Huu, S. Marin, M.J. Ledoux, M. Weibel, G. Ehret, M. Benaissa, E. Peschiera, and J. Guille, Appl. Catal. B: Env., 4 (1994) 45.

    Google Scholar 

  67. M. Benaissa, C. Pham-Huu, J. Werckmann, C. Crouzet, and M.J. Ledoux, Catal. Today, 23 (1995) 283.

    Google Scholar 

  68. C. Serre, F. Garin, G. Belot, and G. Maire, J. Catal., 141 (1993) 1; C. Serre, F. Garin, G. Belot, and G. Maire, J. Catal., 141 (1993) 9.

    Google Scholar 

  69. P. Stobbe, H. G. Petersen, J. W. Hoj, and S. C. Sorenson, SAE Tech. Paper. Ser. 932495, 1 (1993).

  70. S. C. Sorenson, J. W. Hoj, and P. Stobbe, SAE Tech. Paper. Ser. 940236, 55 (1994).

  71. N. Taoka, K. Ohno, S. Hong, H. Sato, Y. Yoshida, T. Komori, SAE Tech. Paper Ser. 2001-01-0191, 1 (2001).

  72. S. J. Ijima, Nature, 354 (1991) 56.

    Google Scholar 

  73. J. M. Bonard, L. Forro, D. Ugarte, W. A. de Herr, and A. Châtelain, Eur. Chem. Chronicle, 1(3) (1998) 9.

    Google Scholar 

  74. Ch. Laurent, E. Flahaut, A. Peigney, A. Rousset, New J. Chem., (1998) 1229.

  75. P. M. Ayajan, Chem. Mater., 11 (1999) 3862.

    Google Scholar 

  76. R. Tenne, M. Homyonfer, and Y. Feldman, Chem. Mater., 10 (1998) 3225.

    Google Scholar 

  77. M. Remskar, Z. Skraba, M. Regula, C. Ballif, R. Sanjinés, and F. Lévy, Adv. Mater., 10 (1998) 248.

    Google Scholar 

  78. H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl, R. E. Smalley, Nature, 318 (1985) 162.

    Google Scholar 

  79. K. P. de Jong, J. W. Geus, Catal. Rev.-Sci. Eng., 42 (2000) 481.

    Google Scholar 

  80. N. M. Rodriguez, A. Chambers, R. T. K. Baker, Langmuir, 11 (1995) 3862.

    Google Scholar 

  81. C. Pham-Huu, N. Keller, G. Ehret, and M. J. Ledoux, J. Catal., 200 (2001) 400.

    Google Scholar 

  82. R. T. K. Baker, K. Laubernds, A. Wootsch, and Z. Paal, J. Catal., 193 (2000) 165.

    Google Scholar 

  83. A. Chambers, T. Nemes, N. M. Rodriguez, and R. T. K. Baker, J. Phys. Chem. B, 102 (1998) 2251.

    Google Scholar 

  84. F. Salman, C. Park, and R. T. K. Baker, Catal. Today, 53 (1999) 385.

    Google Scholar 

  85. A. C. Dillon, K. M. Jones, T. A. Bekkedahl, C. H. Kiang, D. S. Bethune, and M. J. Heben, Nature, 386 (1997) 377.

    Google Scholar 

  86. C. Liu, Y. Y. Fan, M. Liu, H. T. Cong, H. M. Cheng, and M. S. Dresselhaus, Science, 286, (1999) 1127.

    Google Scholar 

  87. E. G. Derouane, J. M. André, and A. A. Lucas, J. Catal., 110 (1988) 58.

    Google Scholar 

  88. C. Job, Sicat, 14 avenue Hoche, 75008 Paris, Fra

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ledoux, M.J., Pham-Huu, C. Silicon Carbide: A Novel Catalyst Support for Heterogeneous Catalysis. CATTECH 5, 226–246 (2001). https://doi.org/10.1023/A:1014092930183

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1014092930183

Keywords

Navigation