Abstract
A method of molecular dynamics is used to investigate friction anisotropy observed on a hexagonally packed organic monolayer of straight-chain molecules, which tilt in a specific direction. A rigid gold slider with a single atomic protuberance is used as a model of a typical atomic force microscope tip apex. The friction anisotropy is observed at 50 K, which is below the melting point of rotation around a long axis of the molecule. The anisotropic frictional behavior is that sliding in directions normal to the direction of the collective tilt of the molecules results in the maximum friction force. The origin of the anisotropy is attributed to anisotropy in lateral compliance in the monolayer.
Similar content being viewed by others
References
R.W. Carpick and M. Salmeron, Chem. Rev. 97 (1998) 1163.
J. Colchero, E. Meyer and O. Marti, in: Handbook of Micro/Nano Tribology, 2nd Ed., ed. B. Bhushan (CRC Press, Boca Raton, 1999) p. 273.
E. Meyer, R. Overney, D. Brodbeck, L. Howald, R. Lüthi, J. Frommer and H.-J. Güntherodt, Phys. Rev. Lett. 69 (1992) 1777.
R.M. Overney, E. Meyer, J. Frommer, D. Brodbeck, R. Lüthi, L. Howald, H.-J. Güntherodt, M. Fujihira, H. Takano and Y. Gotoh, Nature 359 (1992) 133.
C.M. Mate, G.M. McClelland, R. Erlandsson and S. Chiang, Phys. Rev. Lett. 59 (1987) 1942.
G. Meyer and N.M. Amer, Appl. Phys. Lett. 57 (1990) 2089.
O. Marti, J. Colchero and J. Mlynek, Nanotechnology 1 (1990) 141.
R.M. Overney, H. Takano, M. Fujihira, W. Paulus and H. Ringsdorf, Phys. Rev. Lett. 72 (1994) 3546.
M. Liley, D. Gourdon, D. Stamou, U. Meseth, T.M. Fischer, C. Lautz, H. Stahlberg, H. Vogel, N.A. Burnham and C. Duschl, Science 280 (1998) 273.
U. Gehlert, J. Fang and C.M. Knobler, J. Phys. Chem. B 102 (1998) 2614.
M. Hirano, K. Shinjo, R. Kaneko and Y. Murata, Phys. Rev. Lett. 67 (1991) 2642.
J. Kerssemmakers and J.T.M. De Hosson, Appl. Phys. Lett. 67 (1995) 347.
H. Bluhm, U.D. Schwarz and R. Wiesendanger, Phys. Rev. B 57 (1998) 161.
J.A. Harrison, S.J. Stuart and D.W. Brenner, in: Handbook of Micro/ Nano Tribology, 2nd Ed., ed. B. Bhushan (CRC Press, Boca Raton, 1999) p. 525.
G.A. Tomlinson, Phil. Mag. 77 (1929) 905.
F.C. Frenkel and T. Kontorova, Zh. Eksp. Teor. Fiz. 8 (1938) 1340.
U. Landman, W.D. Luedtke and M.W. Ribarsky, J. Vac. Sci. Technol. A 7 (1989) 2829.
J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, Phys. Rev. B 46 (1992) 9700.
J.N. Glosli and G.M. McClelland, Phys. Rev. Lett. 70 (1993) 1960.
K.J. Tupper and D.W. Brenner, Thin Solid Films 253 (1994) 185.
J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, J. Phys. Chem. 97 (1993) 6573.
J.A. Harrison, R.J. Colton, C.T. White and D.W. Brenner, Wear 168 (1993) 127.
J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, Thin Solid Films 260 (1995) 205.
A. Koike and M. Yoneya, J. Chem. Phys. 105 (1996) 6060.
A. Koike and M. Yoneya, Langmuir 13 (1997) 1718.
T. Bonner and A. Baratoff, Surf. Sci. 377-379 (1997) 1082.
A.B. Tutein, S.J. Stuart and J.A. Harrison, Langmuir 16 (2000) 291.
M. Cieplak, E.D. Smith and M.O. Robbins, Science 265 (1994) 1209.
M.O. Robbins and E.D. Smith, Langmuir 12 (1996) 4543.
J.B. Sokoloff, Phys. Rev. B 42 (1990) 760.
T. Ohzono, J.N. Glosli and M. Fujihira, Jpn. J. Appl. Phys. 37 (1998) 6335.
T. Ohzono, J.N. Glosli and M Fujihira, Jpn. J. Appl. Phys. 38 (1999) L 675.
M. Fujihira and T. Ohzono, Jpn. J. Appl. Phys. 38 (1999) 3918.
M. Hirano and K. Shinjo, Phys. Rev. B 41 (1990) 11837.
P. van der Ploeg and H.J.C. Berendsen, J. Chem. Phys. 76 (1982) 3271.
J.P. Ryckaert and A. Bellemans, Chem. Phys. Lett. 30 (1975) 123.
L.J. Dunfield, A.W. Burgess and H.A. Scherage, J. Phys. Chem. 82 (1978) 2609.
J. Hauntman and M.L. Klein, J. Chem. Phys. 91 (1989) 4994.
T.K. Xia, J. Ouyang, M.W. Ribarsky and U. Landman, Phys. Rev. Lett. 69 (1992) 1967.
M. Fujihira, in: Micro/Nanotribology and Its Applications, ed. B. Bhushan (Kluwer Academic, Dordrecht, 1997) p. 239.
H.J.C. Berendsen, J.P.M. Postma, W.F. van Gunsteren, A. Dinola and J.R. Haak, J. Chem. Phys. 81 (1984) 3684.
I.L. Singer, S. Fayeulle and P.D. Ehni, Wear 149 (1991) 375.
T. Ohzono and M. Fujihira, to be submitted.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ohzono, T., Fujihira, M. Simulations of friction anisotropy on ordered organic monolayer. Tribology Letters 9, 63–67 (2000). https://doi.org/10.1023/A:1018804410641
Issue Date:
DOI: https://doi.org/10.1023/A:1018804410641