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The Effect of Yttrium Oxide on the Microstructure and Properties of Ceramics Based on Lanthanum Hexaaluminate Synthesized by the Sol–Gel Method

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Abstract

The effect of a sintering aid, yttrium oxide, on the properties of ceramic materials based on lanthanum hexaaluminate synthesized by a sol–gel method is studied. The synthesis of a sol of ternary oxide composition conducted via hydrolysis of a mixed salt solution leads to the formation of particles with a “nucleus – shell”-type structure. The synthesis of lanthanum hexaaluminate with the participation of these particles proceeds at 1000 – 1100°C, and the sintering of ceramic at 1400 – 1500°C. Ceramic based on yttrium-containing lanthanum hexaaluminate exhibits improved strength properties.

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REFERENCES

  1. A. G. Portnoi and M. P. Timofeeva, “Synthesis and properties of rare-earth monoaluminates,” Izv. Akad. Nauk SSSR, Ser. Neorg. Mater., 1(19), 1598–1600 (1965).

    Google Scholar 

  2. N. A. Toropov, I. A. Bondar, and Yu. I. Smolin, Rare-Earth Silicates and Their Analogs [in Russian], Nauka, Leningrad (1971).

    Google Scholar 

  3. S. L. Conwell and W. P. Wood, U.S. Patent No. 5511648, IPC 6 C 09 C1/68, Alpha Alumina-Based Abrasive Grain.

  4. M. Yasuoka, K. Hirao, M. Brita, and Sh. Kanzaki, “High-strength and high-fracture-toughness ceramics in the Al2O3/LaAl11O18 systems,” J. Am. Ceram. Soc., 78(7), 1853–1856 (1995).

    Google Scholar 

  5. D. Yu. Ostrovoi, G. A. Gogotsi, S. A. Suvorov, and A. P. Shevchik, “Strain and fracture of a ceramic based on lanthanum chromite,” Ogneup. Tekh. Keram., No. 7/8, 10–20 (2002).

    Google Scholar 

  6. E. V. Dudnik, Z. A. Zaitseva, A. V. Shevchenko, and L. M. Lopato, “Sintering of ultradisperse powders based on zirconium dioxide,” Poroshk. Metall., No. 5/6, 43–48 (1995).

    Google Scholar 

  7. Yu. Oya, “The effect of additives on the microstructure and bending strength of aluminum titanate-based ceramics,” Ege Kekaishi, 93(6), 315–321 (1985).

    Google Scholar 

  8. M. Kosaka, E. Onomura, and K. Hayashi, “Strength and structure of components sintered from the powdered silicon carbide, yttrium oxide, and aluminum oxide,” Ege Kekaishi, 93(7), 415–423 (1985).

    Google Scholar 

  9. M. A. Gülgün, V. Putlaev, and M. Rühle, “Effects of yttrium doping α-alumina: 1. Microstructure and microchemistry,” J. Am. Chem. Soc., 82(7), 1849–1856 (1999).

    Google Scholar 

  10. J. Cho, M. P. Harmer, H. M. Chan, and J. M. Ricman, “Effect of yttrium and lanthanum on the tensile creep behavior of aluminum oxide,” J. Am. Chem. Soc., 80(4), 1013–1017 (1997).

    Google Scholar 

  11. M. A. Gülgün, Chr. Elsasser, S. Kostmeier, and M. Rühle, “Structure and composition of grain boundaries in α-Al2O3,” Am. Ceram. Soc., 305 (1999).

  12. J. Fang, M. P. Harmer, and N. M. Chan, “Effect of yttrium and lanthanum on the final-stage sintering behavior of ultrahigh-purity alumina,” J. Am. Chem. Soc., 80(8), 2005–2012 (1997).

    Google Scholar 

  13. B. N. Dudkin and A. Yu. Bugaeva, “Microcrystalline corundum — lanthanum aluminate-based ceramics produced by the sol-gel method,” in: Exploratory Research in the Field of New Nonmetallic Materials, Proc. of the Komi Research Center, Institute of Chemistry, Ural Branch of the Russian Academy of Sciences, Issue 161 [in Russian], Syktyvkar (1999).

  14. B. N. Dudkin, A. Yu. Bugaeva, and G. G. Zainullin, “Effect of an yttrium oxide dopant on the microstructure and properties of lanthanum aluminate ceramics with a β-alumina structure,” in: Proc. of an All-Union Research Conference “Ceramic Materials: Production and Application,” Moscow, 28–29 May [in Russian], Moscow (2003), pp. 85–88.

  15. Yu. G. Frolov, A Course in Colloid Chemistry. Surface Effects and Dispersed Systems [in Russian], Khimiya, Moscow (1988).

    Google Scholar 

  16. S. Gregg and K. Sing, Adsorption, Surface Area and Porosity, Academic Press, London (1967).

    Google Scholar 

  17. N. D. Topor, L. P. Ogorodova, and L. V. Mel'chakova, Thermal Analysis of Minerals and Inorganic Compounds [in Russian], Moscow State University (MGU), Moscow (1984).

    Google Scholar 

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Dudkin, B.N., Bugaeva, A.Y., Zainullin, G.G. et al. The Effect of Yttrium Oxide on the Microstructure and Properties of Ceramics Based on Lanthanum Hexaaluminate Synthesized by the Sol–Gel Method. Refractories and Industrial Ceramics 45, 31–35 (2004). https://doi.org/10.1023/B:REFR.0000023348.19718.73

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  • DOI: https://doi.org/10.1023/B:REFR.0000023348.19718.73

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