Abstract
Research based on 15N stable isotope variations in natural compounds is expanding in scientific fields such as biogeochemistry (isotope fractionation effects measurements1–7), metabolic studies8,9, hydrology (research of NO3− pollution origin in aquifers10–14), agronomy (estimate of N2 symbiotic fixation by legumes15–17) and oceanography (determination of the source of sedimentary nitrogen18–21). However, intercomparison of results obtained in different laboratories is a problem due to the lack of intercalibrated standards. Atmospheric nitrogen has been chosen by many investigators as a standard20,22,23 and I present here a simple method for the preparation of atmospheric N2 as a standard for δ15N expression with excellent reproducibility. The results indicate a wide homogeneity in isotopic composition of atmospheric nitrogen which appears to be a reliable standard for 15N natural abundance measurements.
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Mariotti, A. Atmospheric nitrogen is a reliable standard for natural 15N abundance measurements. Nature 303, 685–687 (1983). https://doi.org/10.1038/303685a0
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DOI: https://doi.org/10.1038/303685a0
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