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Phase behaviour of concentrated suspensions of nearly hard colloidal spheres

Nature volume 320, pages 340–342 (1986)Cite this article

Abstract

Suspensions of spherical colloidal particles in a liquid show a fascinating variety of phase behaviour which can mimic that of simple atomic liquids and solids. ‘Colloidal fluids’1–4, in which there are significant short-range correlations between the positions of neighbouring particles, and ‘colloidal crystals’5–7, which have long-range spatial order, have been investigated extensively. We report here a detailed study of the phase diagram of suspensions of colloidal spheres which interact through a steep repulsive potential. With increasing particle concentration we observed a progression from colloidal fluid, to fluid and crystal phases in coexistence, to fully crystallized samples. At the highest concentrations we obtained very viscous samples in which full crystallization had not occurred after several months and in which the particles appeared to be arranged as an amorphous ‘colloidal glass’. The empirical phase diagram can be reproduced reasonably well by an effective hard-sphere model. The observation of the colloidal glass phase is interesting both in itself and because of possible relevance to the manufacture of high-strength ceramics8.

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Authors and Affiliations

  1. Royal Signals and Radar Establishment, St Andrews Road, Malvern, WR14 3PS, UK

    P. N. Pusey & W. van Megen

  2. Department of Applied Physics, Royal Melbourne Institute of Technology, Melbourne, Australia

    W. van Megen

Authors
  1. P. N. Pusey
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  2. W. van Megen
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Pusey, P., van Megen, W. Phase behaviour of concentrated suspensions of nearly hard colloidal spheres. Nature 320, 340–342 (1986). https://doi.org/10.1038/320340a0

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