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A silicate weathering mechanism linking increases in marine 87Sr/ 86Sr with global glaciation

Abstract

THE 87Sr/ 86Sr ratio of sea water is generally regarded as a proxy for the rate of chemical weathering of the continents. Interpretation of the 87Sr/86Sr record in marine limestones requires an understanding of how changes in this quantity are linked to climate and tectonic events. A connection between the strontium isotope record and the extent of global glaciation has been proposed1 –8, but without a well established mechanism. Glaciation may influence marine 87Sr/ 86Sr by changing global riverine Sr fluxes (that is, rock weathering rates) and/or 87Sr/86Sr ratios (that is, relative mineral weathering rates). Here we investigate how the 87Sr/86Sr release from silicate weathering is affected by glaciation, using the Sr isotope systematics of granitoid soils on alpine glacial moraines in the Wind River Range, Wyoming. We observe a negative correlation between the 87Sr/86Sr ratio of exchangeable Sr in soils and the soil age, indicating that the 87Sr/86Sr ratio of Sr released in the early stages of weathering is significantly higher than in later stages. We estimate that this mechanism can increase global riverine 87Sr/86Sr by an average of 0.0002 during periods of glacial–interglacial cycling. When superimposed on long-term trends controlled by tectonic processes2–7,9,10, this shift can account for the correlation between the rate of change of marine 87Sr/86Sr and the intensity of glaciation over at least the past 10 Myr.

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References

  1. Armstrong, R. L. Nature 230, 132–133 (1971).

    ADS  CAS  Google Scholar 

  2. DePaolo, D. J. Geology 14, 103–106 (1986).

    Article  ADS  CAS  Google Scholar 

  3. Raymo, M. E., Ruddiman, W. F. & Froelich, P. N. Geology 16, 649–653 (1988).

    Article  ADS  CAS  Google Scholar 

  4. Hodell, D. A., Mueller, P. A., McKenzie, J. A. & Mead, G. A. Earth planet. Sci. Lett. 92, 165–178 (1989).

    Article  ADS  CAS  Google Scholar 

  5. Hodell, D. A., Mead, G. A. & Mueller, P. A. Chem. Geol. 80, 291–307 (1990).

    CAS  Google Scholar 

  6. Capo, R. C. & DePaolo, D. J. Science 249, 51–55 (1990).

    Article  ADS  CAS  Google Scholar 

  7. Miller, K. G., Feigenson, M. D., Wright, J. D. & Clement, B. M. Paleoceanography 6, 33–52 (1991).

    Article  ADS  Google Scholar 

  8. Blum, J. D., Erel, Y. & Brown, K. Geochim. cosmochim. Acta 58, 5019–5025 (1993).

    Article  ADS  Google Scholar 

  9. Richter, F. M. & Turekian, K. K. Earth planet. Sci. Lett. 119, 121–131 (1993).

    Article  ADS  CAS  Google Scholar 

  10. Palmer, M. R. & Edmond, J. M. Earth planet. Sci. Lett. 92, 11–26 (1989).

    Article  ADS  CAS  Google Scholar 

  11. Naylor, R. S., Steiger, R. H. & Wasserburg, G. J. Geochim. cosmochim. Acta 34, 1133–1159 (1970).

    Article  ADS  CAS  Google Scholar 

  12. Hurley, P. M. & Rand, J. R. Science 164, 1229–1242 (1969).

    Article  ADS  CAS  Google Scholar 

  13. Richmond, G. M. Quad. Map GQ-1138, scale 1:24,000 (US Geol. Surv., Washington DC, 1973).

    Google Scholar 

  14. Mahaney, W. C. & Halvorson, D. L. in Rates of Chemical Weathering of Rocks and Minerals (eds Colman, S. M. & Dethier, D. P.) 147–167 (Academic, Orlando, 1986).

    Google Scholar 

  15. Gosse, J., Klein, J., Evenson, E., Lawn, B. & Middleton, R. Circ. No. 1107 114 (US Geol. Surv., Denver, Colorado, 1994).

  16. Evenson, E., Klein, J., Lawn, B., Middleton, R. & Gosse, J. Geol. Soc. Am. Abstr. Progm. 26, A-511 (1994).

    Google Scholar 

  17. Ross, G. J., Wang, C. & Protz, R. in Correlation of Quaternary Chronologies (ed. Mahaney, W. C.) 191–202 (Geobooks, Norwich, UK, 1983).

    Google Scholar 

  18. Hughes, T. J. et al. in The Last Great Ice Sheets (eds Denton, G. H. & Hughes, T. J.) 275–318 (Wiley, New York, 1981).

    Google Scholar 

  19. Taylor, S. R., McLennan, S. M. & McCulloch, M. T. Geochim. cosmochim. Acta 47, 1897–1905 (1983).

    Article  ADS  CAS  Google Scholar 

  20. Wadleigh, M. A., Veizer, J. & Brooks, C. Geochim. cosmochim. Acta 49, 1727–1736 (1985).

    Article  ADS  CAS  Google Scholar 

  21. Bickle, M. J. Nature 367, 699–704 (1994).

    Article  ADS  CAS  Google Scholar 

  22. Kennett, J. P. Init. Rep. DSDP Leg, 90, 1388–1412 (1986).

    Google Scholar 

  23. Malmgren, B. A. & Berggren, W. A. Paleoceanography 2, 445–456 (1987).

    Article  ADS  Google Scholar 

  24. Shackleton, N. J. et al. Nature 307, 620–623 (1984).

    Article  ADS  CAS  Google Scholar 

  25. Kennett, J. P. & von der Borch, C. Init. Rep. DSDP Leg 90, 1493–1517 (1986).

    CAS  Google Scholar 

  26. Henderson, G. M., Martel, D. J., O'Nions, R. K. & Shackleton, N. J. Mineral. Mag. 58A, 404–405 (1994).

    Article  ADS  Google Scholar 

  27. Clemens, S. C., Gromet, P. & Farrell, J. W. Mineralog. Mag. 58A, 178–179 (1994).

    Article  Google Scholar 

  28. Oslick, J. S., Miller, K. G., Feigenson, M. D. & Wright, J. D. Paleoceanography 9, 427–443 (1994).

    Article  ADS  Google Scholar 

  29. Hodell, D. A. & Woodruff, F. Paleoceanography 9, 405–426 (1994).

    Article  ADS  Google Scholar 

  30. Ruddiman, W. F. & Kutzbach, J. E. J. geophys. Res. 94, 18409–18427 (1989).

    Article  ADS  Google Scholar 

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Blum, J., Erel, Y. A silicate weathering mechanism linking increases in marine 87Sr/ 86Sr with global glaciation. Nature 373, 415–418 (1995). https://doi.org/10.1038/373415a0

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