An experimental set-up has been devised to monitor mechanochemical processes in situ, yielding direct insights into mechanistic and kinetic aspects of solid-state reactions that are promoted by grinding, such as the synthesis of metal–organic frameworks.
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References
Boldyrev, V. V. & Tkáčová, K. J. Mater. Synth. Proc. 8, 121–132 (2000).
Takacs, L. J. Metals 52, 12–13 (2000).
Faraday, M. Quart. J. Sci. Liter. Arts 8, 374–376 (1820).
Takacs, L. J. Therm. Anal. Calorim. 90, 81–84 (2007).
Thomas, J. M. Chem. Britain 6, 60–64 (February 1970).
Lazuen Garay, A., Pichon, A. & James, S. L. Chem. Soc. Rev. 36, 846–855 (2007).
James, S. L. et al. Chem. Soc. Rev. 41, 413–447 (2012).
Friščić, T. et al. Nature Chem. 5, 66–73 (2013).10.1038/nchem.1505
Cheung, E. Y. et al. J. Am. Chem. Soc. 125, 14658–14659 (2003).
Fujii, K. et al. Chem. Commun. 46, 7572–7574 (2010).
Friščić, T., Meštrović, E., Škalec Šamec, D., Kaitner, B. & Fábián, L. Chem. Eur. J. 15, 12644–12652 (2009).
Beldon, P. J. et al. Angew. Chem. Int. Ed. 49, 9640–9643 (2010).
Zhang, J.-P., Zhang, Y.-B., Lin, J.-B. & Chen, X.-M. Chem. Rev. 112, 1001–1033 (2012).
Rietveld, H. M. J. Appl. Crystallogr. 2, 65–71 (1969).
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Harris, K. How grinding evolves. Nature Chem 5, 12–14 (2013). https://doi.org/10.1038/nchem.1539
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DOI: https://doi.org/10.1038/nchem.1539
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