Low temperature synthesis and structures of alkaline earth metal chalcogenides Ba3Cu4SbS6OH, BaCuSbS3 and BaCu2S2

Zhimin Ma; Fan Weng; Qiuran Wang; Qun Tang; Ganghua Zhang; Chong Zheng; Ray P. S. Han; Fuqiang Huang

doi:10.1039/C3RA46878J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Low temperature synthesis and structures of alkaline earth metal chalcogenides Ba₃Cu₄SbS₆OH, BaCuSbS₃ and BaCu₂S₂†

Zhimin Ma,^a Fan Weng,^b Qiuran Wang,^b Qun Tang,^b Ganghua Zhang,^c Chong Zheng,^d Ray P. S. Han^a and Fuqiang Huang*^abc

Author affiliations

* Corresponding authors

^a Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China
E-mail: huangfq@pku.edu.cn
Fax: +86-10-62767628
Tel: +86-10-62758225

^b State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

^c State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

^d Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115, USA

Abstract

For the first time, alkaline earth metal multinary chalcogenides Ba₃Cu₄SbS₆OH (1), BaCuSbS₃ (2) and BaCu₂S₂ (3) were synthesized via hydrothermal methods at low temperatures. The structures of these three compounds contain three-dimensional channeled frameworks that are constructed by different types of Cu/S chains.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3RA46878J
Article type: Communication
Submitted: 20 Nov 2013
Accepted: 11 Jun 2014
First published: 12 Jun 2014

Download Citation

RSC Adv., 2014,4, 28937-28940

Permissions

Request permissions

Low temperature synthesis and structures of alkaline earth metal chalcogenides Ba₃Cu₄SbS₆OH, BaCuSbS₃ and BaCu₂S₂

Z. Ma, F. Weng, Q. Wang, Q. Tang, G. Zhang, C. Zheng, R. P. S. Han and F. Huang, RSC Adv., 2014, 4, 28937 DOI: 10.1039/C3RA46878J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

RSC Advances