Issue 41, 2015

Role of multiwalled carbon nanotubes (MWCNTs) on rheological, thermal and electrical properties of PC/ABS blend

Abstract

The main objective of this work was to probe the effect of multiwalled carbon nanotubes (MWCNTs) on the rheological, electrical and thermal properties of polycarbonate (PC)/acrylonitrile butadiene styrene (ABS) 75/25 blend prepared by simultaneous melt blending. The results of thermodynamics measurements suggested that the MWCNTs were preferentially localized in the interface of the PC and ABS; however, melt linear viscoelastic measurements and TEM results showed a greater affinity of MWCNTs towards the PC matrix. This was also supported by the electrical percolation threshold observed at low MWCNT content. The microstructure of the samples was analyzed by melt linear viscoelastic experiments and electron microscopy, which revealed that the MWCNTs were dispersed quite homogeneously in the PC matrix. The electrical conductivity and electromagnetic interference shielding efficiency (EMI SE) of the blend nanocomposite samples were enhanced with increasing the loading level of MWCNTs. Finally, thermal analysis was employed as a complementary experiment to provide further evidence for MWCNTs' partitioning.

Graphical abstract: Role of multiwalled carbon nanotubes (MWCNTs) on rheological, thermal and electrical properties of PC/ABS blend

Article information

Article type
Paper
Submitted
06 Mar 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

RSC Adv., 2015,5, 32880-32890

Author version available

Role of multiwalled carbon nanotubes (MWCNTs) on rheological, thermal and electrical properties of PC/ABS blend

A. Rostami, M. Masoomi, M. J. Fayazi and M. Vahdati, RSC Adv., 2015, 5, 32880 DOI: 10.1039/C5RA04043D

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