Issue 16, 2016
From the journal:

Physical Chemistry Chemical Physics

Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries†

Christos D. Malliakas,ab   Kevin Leung,c   Krzysztof Z. Pupek,d   Ilya A. Shkrob*e  and  Daniel P. Abrahame  

* Corresponding authors

a Materials Science Division, Argonne National Laboratory, 9700 S. Cass Ave, Argonne, IL 60439, USA

b Department of Chemistry, Northwestern University, Evanston, IL 60208, USA

c Sandia National Laboratories, Albuquerque, New Mexico 87185, USA

d Energy Systems Division and Materials Engineering Research Facility, Argonne National Laboratory, 9700 S. Cass Ave, Argonne, IL 60439, USA

e Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Ave, Argonne, IL 60439, USA
E-mail: Shkrob@anl.gov

Abstract

Fluorinated carbonates are pursued as liquid electrolyte solvents for high-voltage Li-ion batteries. Here we report aggregation of [Li+(FEC)3]n polymer species in fluoroethylene carbonate containing electrolytes and scrutinize the causes for this behavior.

Graphical abstract: Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CP01157H
Article type
Communication
Submitted
20 Feb 2016
Accepted
21 Mar 2016
First published
31 Mar 2016

Phys. Chem. Chem. Phys., 2016,18, 10846-10849

Permissions

Request permissions

Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

C. D. Malliakas, K. Leung, K. Z. Pupek, I. A. Shkrob and D. P. Abraham, Phys. Chem. Chem. Phys., 2016, 18, 10846 DOI: 10.1039/C6CP01157H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements