Application of metal organic frameworks M(bdc)(ted)0.5 (M = Co, Zn, Ni, Cu) in the oxidation of benzyl alcohol

Ling Peng; Shujie Wu; Xiaoyuan Yang; Jing Hu; Xiaoran Fu; Qisheng Huo; Jingqi Guan

doi:10.1039/C6RA12799A

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Application of metal organic frameworks M(bdc)(ted)_0.5 (M = Co, Zn, Ni, Cu) in the oxidation of benzyl alcohol†

Ling Peng,^a Shujie Wu,^a Xiaoyuan Yang,^a Jing Hu,^a Xiaoran Fu,^a Qisheng Huo^b and Jingqi Guan*^a

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* Corresponding authors

^a College of Chemistry, Jilin University, Changchun, P. R. China
E-mail: guanjq@jlu.edu.cn

^b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Abstract

The selective oxidation of benzyl alcohol to benzaldehyde is an important process in heterogeneous catalysis and green organic chemistry. Herein, we investigated the effect of different metal ions in the metal organic framework M(bdc)(ted)_0.5 (M = Co, Zn, Ni, Cu, bdc = 1,4-benzenedicarboxylate, ted = triethylenediamine) on the catalytic activity of benzyl alcohol oxidation. The catalytic results demonstrated that Co(bdc)(ted)_0.5 achieved good benzyl alcohol conversion (81.8%) and benzaldehyde selectivity (>99%) by using O₂ as the oxidant. The catalysts could be reused several times without significant degradation in activity.

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Article information

DOI: https://doi.org/10.1039/C6RA12799A
Article type: Paper
Submitted: 17 May 2016
Accepted: 25 Jul 2016
First published: 01 Aug 2016

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RSC Adv., 2016,6, 72433-72438

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Application of metal organic frameworks M(bdc)(ted)_0.5 (M = Co, Zn, Ni, Cu) in the oxidation of benzyl alcohol

L. Peng, S. Wu, X. Yang, J. Hu, X. Fu, Q. Huo and J. Guan, RSC Adv., 2016, 6, 72433 DOI: 10.1039/C6RA12799A

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