Issue 8, 2005
From the journal:

Chemical Communications

NO2 disproportionation for the IR characterisation of basic zeolites

Olivier Marie,a   Nicolas Malicki,a   Catherine Pommier,b   Pascale Massiani,b   Ann Vos,†c   Robert Schoonheydt,c   Paul Geerlings,d   Carlos Henriquese  and  Fréderic Thibault-Starzyk*af  

* Corresponding authors

a Laboratoire Catalyse et Spectrochimie – UMR 6506 – ENSICaen, 6 Bd Mal Juin, Caen cedex, France
E-mail: fts@ensicaen.fr
Fax: +33 231 452 822
Tel: +33 231 452 821

b Laboratoire de Réactivité de Surface, Université Pierre et Marie Curie, 4 Place Jussieu, Paris cedex 05, France

c Centrum voor Oppervlaktechemie en Katalyse, Katholieke Universiteit Leuven, Kasteelpark Arenberg 23, Leuven, Belgium

d Eenheid Algemene Chemie, Vrije Universiteit Brussel, Pleinlaan 2, Brussels, Belgium

e Departamento Engenharia Quimica, Av. Rovisco Pais, Instituto Superior Tecnico, Lisboa, Portugal

f Churchill College, Cambridge, UK

Abstract

NO2 disproportionation on alkaline zeolites is used to generate nitrosonium (NO+) and nitrate ions on the surface, and the infrared vibrations observed are very sensitive to the cation chemical hardness and to the basicity of zeolitic oxygen atoms.

Graphical abstract: NO2 disproportionation for the IR characterisation of basic zeolites

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Article information

DOI
https://doi.org/10.1039/B414664F
Article type
Communication
Submitted
23 Sep 2004
Accepted
26 Nov 2004
First published
10 Jan 2005

Chem. Commun., 2005, 1049-1051

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NO2 disproportionation for the IR characterisation of basic zeolites

O. Marie, N. Malicki, C. Pommier, P. Massiani, A. Vos, R. Schoonheydt, P. Geerlings, C. Henriques and F. Thibault-Starzyk, Chem. Commun., 2005, 1049 DOI: 10.1039/B414664F

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