Issue 9, 2007
From the journal:

New Journal of Chemistry

Novel polymer-supported ruthenium and iron complexes that catalyze the conversion of epoxides into diols or diol mono-ethers: clean and recyclable catalysts†

Sun Hwa Lee,a   Eun Yong Lee,a   Dong-Woo Yoo,b   Sung Jin Hong,a   Jung Hwan Lee,a   Han Kwak,a   Young Min Lee,a   Jinheung Kim,c   Cheal Kim*a  and  Jin-Kyu Lee*b  

* Corresponding authors

a Department of Fine Chemistry and the Eco-Product and Materials Education Center, Seoul National University of Technology, Seoul, Korea
E-mail: chealkim@snut.ac.kr
Fax: +82 2 973 9149
Tel: +82 2 970 6693

b School of Chemistry, Seoul National University, Seoul, Korea
E-mail: jinklee@snu.ac.kr
Fax: +82 2 882 1080
Tel: +82 2 880 8830

c Department of Chemistry and Division of Nano Sciences, Ewha Womans University, Seoul, Korea

Abstract

Polymer-supported metal (Fe or Ru) complexes for epoxide ring opening reactions were successfully prepared by anchoring the bis(2-picolyl)amine ligand onto the polymer poly(chloromethylstyrene-co-divinylbenzene) (PCD); the catalysts showed heterogeneous catalytic activity and easy recyclability in the ring opening reactions of various epoxide substrates with methanol or H2O at room temperature under mild and neutral conditions.

Graphical abstract: Novel polymer-supported ruthenium and iron complexes that catalyze the conversion of epoxides into diols or diol mono-ethers: clean and recyclable catalysts

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Article information

DOI
https://doi.org/10.1039/B707028D
Article type
Letter
Submitted
09 May 2007
Accepted
11 Jul 2007
First published
20 Jul 2007

New J. Chem., 2007,31, 1579-1582

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Novel polymer-supported ruthenium and iron complexes that catalyze the conversion of epoxides into diols or diol mono-ethers: clean and recyclable catalysts

S. H. Lee, E. Y. Lee, D. Yoo, S. J. Hong, J. H. Lee, H. Kwak, Y. M. Lee, J. Kim, C. Kim and J. Lee, New J. Chem., 2007, 31, 1579 DOI: 10.1039/B707028D

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