Chlorodicarbonylrhodium(I) dimer, [Rh(CO)2-Cl]2, or chlorocarbonylbis(triphenylphosphine)rhodium, [(Ph3P)2Rh(CO)Cl], reacts with 2-aryl-azirines under gentle conditions (benzene, room temperature) to afford 2-styryl-indoles.
H. Alper and J. E. Prickett, J. Chem. Soc., Chem. Commun., 1976, 483 DOI: 10.1039/C39760000483
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