Issue 3, 2012
From the journal:

Chemical Communications

Catalytic hydroboration by an imido-hydrido complex of Mo(iv)†

Andrey Y. Khalimon,a   Philip Farha,a   Lyudmila G. Kuzminab  and  Georgii I. Nikonov*a  

* Corresponding authors

a Chemistry Department, Brock University, 500 Glenridge Ave., St. Catharines, ON, Canada
E-mail: gnikonov@brocku.ca
Tel: +1 905 6885550, ext 3350

b Kurnakov Institute of General and Inorganic Chemistry RAS, Leninskii Prosp. 31, Moscow, Russia
E-mail: kuzmina@igic.ras.ru

Abstract

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R′C(O)H to yield imines RCH2N[double bond, length as m-dash]C(H)R′.

Graphical abstract: Catalytic hydroboration by an imido-hydrido complex of Mo(iv)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC14508H
Article type
Communication
Submitted
24 Jul 2011
Accepted
25 Oct 2011
First published
11 Nov 2011

Chem. Commun., 2012,48, 455-457

Permissions

Request permissions

Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

A. Y. Khalimon, P. Farha, L. G. Kuzmina and G. I. Nikonov, Chem. Commun., 2012, 48, 455 DOI: 10.1039/C1CC14508H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements