Issue 1, 2014

Facile preparation of Mn3O4 octahedra and their long-term cycle life as an anode material for Li-ion batteries

Abstract

We describe the simple preparation of octahedral Mn3O4 nanomaterials with a typical diameter around 300–400 nm using a one step dealloying of MnAl alloy at room temperature. The as-made sample exhibits high performance as an anode material for Li-ion batteries. Electrochemical measurements reveal that the Mn3O4 octahedra have an ultralong cycle life with capacity retentions of 81.3% and 77.8% after 500 cycles at 100 and 300 mA g−1, respectively. Moreover, the Mn3O4 octahedra deliver a stable capacity at a high rate of 1000 mA g−1 with a good rate capability. The as-made Mn3O4 octahedra exhibit great potential for application as anode materials for Li-ion batteries with the advantages of unique performance and easy preparation.

Graphical abstract: Facile preparation of Mn3O4 octahedra and their long-term cycle life as an anode material for Li-ion batteries

Article information

Article type
Paper
Submitted
04 Sep 2013
Accepted
11 Oct 2013
First published
11 Oct 2013

J. Mater. Chem. A, 2014,2, 87-93

Facile preparation of Mn3O4 octahedra and their long-term cycle life as an anode material for Li-ion batteries

Q. Hao, J. Wang and C. Xu, J. Mater. Chem. A, 2014, 2, 87 DOI: 10.1039/C3TA13510A

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