The enhanced photoelectrochemical performance of CdS quantum dots sensitized TiO2 nanotube/nanowire/nanoparticle arrays hybrid nanostructures
Abstract
This study aims at improving the photoelectrochemical performance mainly from two aspects: the increased number of heterojunctions and the advantages of nanotube/nanowire/nanoparticle arrays hybrid nanostructures. TiO2 nanoparticles porous layer was sensitized by CdS quantum dots (QDs), and coated on the top of the material, hydrogen-treated TiO2 nanotubes with nanowires, which was also sensitized by CdS QDs (This nanostructure is defined as CdS/H:TTWP). CdS/H:TTWP was successfully fabricated by the methods of electrochemical anodization, successive ionic layer adsorption and reaction (SILAR) and sol–gel. The data from the photoelectrochemical (PEC) performance test shows that the photocurrent density of CdS/H:TTWP is 7.6 mA cm−2 at −0.43 V vs. Ag–AgCl under AM 1.5 G illuminations.