Issue 8, 2014
From the journal:

Chemical Science

Co-crystallized fullerene and a mixed (phthalocyaninato)(porphyrinato) dysprosium double-decker SMM†

Hailong Wang,a   Kang Qian,b   Dongdong Qi,a   Wei Cao,a   Kang Wang,a   Song Gao*b  and  Jianzhuang Jiang*a  

* Corresponding authors

a Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
E-mail: jianzhuang@ustb.edu.cn
Fax: +86 (0)10 6233 2462
Tel: +86 (0)10 6233 2592

b Beijing National Laboratory of Molecular Science State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: gaosong@pku.edu.cn

Abstract

Effective and different inter-molecular interactions between fullerene C60 and tetrapyrrole-based double-decker single molecule magnets (SMMs) of three cocrystallates with different molar ratios rationalize the slight structural changes and different magnetic properties. The presented results indicate that different integration modes between the SMM and conjugated sp2-carbon substrate are able to affect the magnetic properties of the spintronic devices to different degrees, representing the effort towards understanding the effect of the conjugated sp2-carbon substrate on the magnetic properties of SMM spintronic devices at a molecular level.

Graphical abstract: Co-crystallized fullerene and a mixed (phthalocyaninato)(porphyrinato) dysprosium double-decker SMM

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Article information

DOI
https://doi.org/10.1039/C4SC00694A
Article type
Edge Article
Submitted
05 Mar 2014
Accepted
15 Apr 2014
First published
16 Apr 2014

Chem. Sci., 2014,5, 3214-3220

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Co-crystallized fullerene and a mixed (phthalocyaninato)(porphyrinato) dysprosium double-decker SMM

H. Wang, K. Qian, D. Qi, W. Cao, K. Wang, S. Gao and J. Jiang, Chem. Sci., 2014, 5, 3214 DOI: 10.1039/C4SC00694A

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