Issue 10, 2015

Facile synthesis of Z-scheme Ag2CO3/Ag/AgBr ternary heterostructured nanorods with improved photostability and photoactivity

Abstract

Ag-based compounds are regarded as a new family of highly efficient visible-light-driven photocatalytic materials. However, in terms of photocorrosion nature of this type of photocatalyst, resulting in the serious deactivation, it is a huge challenge to develop simple and reliable strategies to synthesize Ag-based heterostructured nanostructures with good structural stability and high photoactivity. In this work, we have developed a facile reaction route, with visible-light induced reduction followed by an anion exchange, to prepare one-dimensional (1D) Ag2CO3/Ag/AgBr ternary heterostructured nanorods (HNRs) with tunable chemical compositions at room temperature. The as-obtained 1D Ag2CO3/Ag/AgBr HNRs exhibit significantly enhanced photostability and photocatalytic activity under visible-light illumination. The origin of enhanced photostability and photoactivity was further investigated by a radical-trapping test, and a possible Z-scheme photocatalytic mechanism has been proposed.

Graphical abstract: Facile synthesis of Z-scheme Ag2CO3/Ag/AgBr ternary heterostructured nanorods with improved photostability and photoactivity

Supplementary files

Article information

Article type
Paper
Submitted
10 Nov 2014
Accepted
22 Jan 2015
First published
23 Jan 2015

J. Mater. Chem. A, 2015,3, 5474-5481

Facile synthesis of Z-scheme Ag2CO3/Ag/AgBr ternary heterostructured nanorods with improved photostability and photoactivity

J. Li, Y. Xie, Y. Zhong and Y. Hu, J. Mater. Chem. A, 2015, 3, 5474 DOI: 10.1039/C4TA06075J

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