Host–guest architectures with a surface confined imine covalent organic framework as two-dimensional host networks

Jiang Sun; Xin Zhou; Shengbin Lei

doi:10.1039/C5CC09276K

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Host–guest architectures with a surface confined imine covalent organic framework as two-dimensional host networks†

Jiang Sun,^a Xin Zhou*^a and Shengbin Lei*^ab

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* Corresponding authors

^a State Key Laboratory of Robotics and System, Harbin Institute of Technology, Harbin, People's Republic of China
E-mail: leisb@hit.edu.cn, zhoux@hit.edu.cn

^b Department of Chemistry, School of Science & Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, People's Republic of China

Abstract

A two-dimensional covalent organic framework (2D COF), synthesized on a highly oriented pyrolytic graphite (HOPG) surface with benzene-1,3,5-tricarbaldehyde and p-phenylenediamine as the precursors, is used as a host to accommodate three guest molecules, coronene, copper phthalocyanine (CuPc), and fluorine-substituted copper phthalocyanine (F₁₆CuPc). The host–guest interaction and dynamic behavior were investigated by scanning tunneling microscopy and density functional theory.

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Article information

DOI: https://doi.org/10.1039/C5CC09276K
Article type: Communication
Submitted: 09 Nov 2015
Accepted: 02 Jun 2016
First published: 08 Jun 2016

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Chem. Commun., 2016,52, 8691-8694

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Host–guest architectures with a surface confined imine covalent organic framework as two-dimensional host networks

J. Sun, X. Zhou and S. Lei, Chem. Commun., 2016, 52, 8691 DOI: 10.1039/C5CC09276K

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Chemical Communications

Host–guest architectures with a surface confined imine covalent organic framework as two-dimensional host networks†

Abstract

Supplementary files

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Host–guest architectures with a surface confined imine covalent organic framework as two-dimensional host networks

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