Thiol-Michael addition miniemulsion polymerizations: functional nanoparticles and reactive latex films

Chen Wang; Shunsuke Chatani; Maciej Podgórski; Christopher N. Bowman

doi:10.1039/C5PY00326A

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Thiol-Michael addition miniemulsion polymerizations: functional nanoparticles and reactive latex films†

Chen Wang,

^a Shunsuke Chatani,^a Maciej Podgórski^ab and Christopher N. Bowman*^a

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* Corresponding authors

^a Department of Chemical and Biological Engineering, University of Colorado, UCB 596, Boulder, Colorado 80303, USA
E-mail: Christopher.bowman@colorado.edu

^b Faculty of Chemistry, Department of Polymer Chemistry, MCS University, pl. Marii Curie Skłodowskiej 5, 20-031 Lublin, Poland

Abstract

Thiol-Michael addition polymerization is successfully implemented in a miniemulsion polymerization system. By off-stoichiometric polymerization between thiols and acrylates, inherently functionalized particles are facilely prepared in a single step. We demonstrate that the latex films from such particles are readily available for further modification and second-stage photo-curing.

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Article information

DOI: https://doi.org/10.1039/C5PY00326A
Article type: Communication
Submitted: 05 Mar 2015
Accepted: 09 Apr 2015
First published: 13 Apr 2015

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Polym. Chem., 2015,6, 3758-3763

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Thiol-Michael addition miniemulsion polymerizations: functional nanoparticles and reactive latex films

C. Wang, S. Chatani, M. Podgórski and C. N. Bowman, Polym. Chem., 2015, 6, 3758 DOI: 10.1039/C5PY00326A

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Polymer Chemistry

Thiol-Michael addition miniemulsion polymerizations: functional nanoparticles and reactive latex films†

Abstract

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Thiol-Michael addition miniemulsion polymerizations: functional nanoparticles and reactive latex films

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