Issue 100, 2015

Large strain response and fatigue-resistant behavior in lead-free Bi0.5(Na0.80K0.20)0.5TiO3–(K0.5Na0.5)MO3 (M = Sb, Ta) ceramics

Abstract

(1 − x)Bi0.5(Na0.80K0.20)0.5TiO3x(K0.5Na0.5)MO3 (M = Sb, Ta) (BNKT20–KNM100x) lead-free piezoelectric ceramics were designed and fabricated using a conventional fabrication process to achieve large strain response in BKNT20-based ceramics. The KNM substitution was found to induce a transition from ferroelectric to relaxor pseudocubic phase, and such transition is accompanied with the significant disruption of ferroelectric order and the shift of the ferroelectric–relaxor transition temperature TF−R down to room temperature. Accordingly, large electric-field-induced strains of 0.39–0.41% (at 80 kV cm−1, equivalently 488–513 pm−1 V), which are derived from a reversible field-induced ergodic relaxor to ferroelectric phase transformation, were obtained in 1.25 mol% KNM-modified compositions near the phase boundary. Moreover, an attractive property for application as actuators was obtained in the present system, compositions near the phase boundary with an ergodic relaxor state exhibited fatigue-free behavior after 106 cycles. Furthermore, unexpected almost fatigue-free behavior was also observed in 0.5 mol% KNM-modified samples with a typical ferroelectric long-range order. Results of the enhanced activation energy (Ea) for electrical conduction suggest the well-observed fatigue-resistant behavior in the present system should be mainly attributed to the lower defect density. These findings give the current material great opportunity for actuator applications demanding improved cycling reliabilities.

Graphical abstract: Large strain response and fatigue-resistant behavior in lead-free Bi0.5(Na0.80K0.20)0.5TiO3–(K0.5Na0.5)MO3 (M = Sb, Ta) ceramics

Article information

Article type
Paper
Submitted
06 Jul 2015
Accepted
22 Sep 2015
First published
22 Sep 2015

RSC Adv., 2015,5, 82605-82616

Large strain response and fatigue-resistant behavior in lead-free Bi0.5(Na0.80K0.20)0.5TiO3–(K0.5Na0.5)MO3 (M = Sb, Ta) ceramics

J. Hao, Z. Xu, R. Chu, W. Li, J. Du and P. Fu, RSC Adv., 2015, 5, 82605 DOI: 10.1039/C5RA13126J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements