Issue 15, 2015

Gelatin-pyrolyzed mesoporous carbon as a high-performance sodium-storage material

Abstract

Nitrogen-containing mesoporous carbons were obtained by co-pyrolyzing gelatin and magnesium citrate between 600 and 900 °C. The presence of magnesium citrate lowers the carbonization temperature and its decomposition product, MgO, works as a template for mesoporous carbon. Fourier-transform infrared (FTIR) and X-ray photoelectron (XPS) spectroscopic studies indicate that the nitrogen in the material exists in the form of pyridinic, pyrrolic and oxidized nitrogen. With high specific surface area, homogeneous pore-size distribution and abundant active sites at the edge of the graphene layer, the pyrolytic carbon shows very high reversible sodium (Na) storage capacities up to 360 mA h g−1 and stable cycling stability.

Graphical abstract: Gelatin-pyrolyzed mesoporous carbon as a high-performance sodium-storage material

Article information

Article type
Paper
Submitted
24 Feb 2015
Accepted
03 Mar 2015
First published
03 Mar 2015

J. Mater. Chem. A, 2015,3, 7849-7854

Author version available

Gelatin-pyrolyzed mesoporous carbon as a high-performance sodium-storage material

Z. Guan, H. Liu, B. Xu, X. Hao, Z. Wang and L. Chen, J. Mater. Chem. A, 2015, 3, 7849 DOI: 10.1039/C5TA01446H

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