Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption

Yun-Wu Li; Hui Yan; Tong-Liang Hu; Hui-Yan Ma; Da-Cheng Li; Su-Na Wang; Qing-Xia Yao; Jian-Min Dou; Jian Xu; Xian-He Bu

doi:10.1039/C6CC09923H

Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption†

Yun-Wu Li,

^ab Hui Yan,^a Tong-Liang Hu,^b Hui-Yan Ma,^a Da-Cheng Li,^a Su-Na Wang,

^a Qing-Xia Yao,^a Jian-Min Dou,*^a Jian Xu*^b and Xian-He Bu

*^b

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China
E-mail: dougroup@163.com

^b School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China
E-mail: jxu@nankai.edu.cn, buxh@nankai.edu.cn

Abstract

Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {Fe₂Na₃}_n chains as SBUs, respectively. Both of them exhibit highly selective CO₂ adsorption over CH₄ and N₂, owing to their abundant multiple active sites.

Chemical Communications

Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption†

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Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption

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