Issue 25, 2016

Modeling the melting temperature of nanoscaled bimetallic alloys

Abstract

The effect of size, composition and dimension on the melting temperature of nanoscaled bimetallic alloys was investigated by considering the interatomic interaction. The established thermodynamics model without any arbitrarily adjustable parameters can be used to predict the melting temperature of nanoscaled bimetallic alloys. It is found that, the melting temperature and interatomic interaction of nanoscaled bimetallic alloys decrease with the decrease in size and the increasing composition of the lower surface energy metal. Moreover, for the nanoscaled bimetallic alloys with the same size and composition, the dependence of the melting temperature on the dimension can be sequenced as follows: nanoparticles > nanowires > thin films. The accuracy of the developed model is verified by the recent experimental and computer simulation results.

Graphical abstract: Modeling the melting temperature of nanoscaled bimetallic alloys

Article information

Article type
Paper
Submitted
15 Mar 2016
Accepted
05 Jun 2016
First published
06 Jun 2016

Phys. Chem. Chem. Phys., 2016,18, 16958-16963

Modeling the melting temperature of nanoscaled bimetallic alloys

M. Li and T. Zhu, Phys. Chem. Chem. Phys., 2016, 18, 16958 DOI: 10.1039/C6CP01742H

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