Issue 66, 2016, Issue in Progress
From the journal:

RSC Advances

Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal–organic framework with high capacity†

Tian Li,a   Chao Li,a   Xiaoshi Hu,a   Xiaobing Lou,a   Huiping Hu,a   Likun Pan, ORCID logo a   Qun Chen,a   Ming Shen*a  and  Bingwen Hu*a  

* Corresponding authors

a State Key Laboratory of Precision Spectroscopy, Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, PR China
E-mail: bwhu@phy.ecnu.edu.cn, shen.ming@outlook.com

Abstract

Metal–organic frameworks (MOFs), are explosively developed as electrode materials for lithium-ion batteries. Mn-BTC MOF possessed low cycling stability. We therefore attempted to improve the electrochemical properties by doping cobalt into the Mn-BTC. Cobalt doped MnCo-BTC MOF greatly improved the cycling stability compared with Mn-BTC. A high capacity of 901 mA h g−1 could be obtained for MnCo-BTC at a rate of 100 mA g−1 after 150 cycles. Even at a high rate of 500 mA g−1, its capacity can still reach 445.3 mA h g−1 after 100 cycles.

Graphical abstract: Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal–organic framework with high capacity

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Article information

DOI
https://doi.org/10.1039/C6RA07727G
Article type
Paper
Submitted
24 Mar 2016
Accepted
17 Jun 2016
First published
27 Jun 2016

RSC Adv., 2016,6, 61319-61324

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Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal–organic framework with high capacity

T. Li, C. Li, X. Hu, X. Lou, H. Hu, L. Pan, Q. Chen, M. Shen and B. Hu, RSC Adv., 2016, 6, 61319 DOI: 10.1039/C6RA07727G

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