SCHEDULED MAINTENANCE
Ultrathin graphene nanosheets derived from rice husks for sustainable supercapacitor electrodes†
Abstract
Graphene nanosheets are synthesized via the carbonization of brown-rice husks followed by a one-stage KOH-activation process for the design of a sustainable electrochemical energy-storage electrode. The graphene nanosheets exhibit an ultra-thin crumpled-silk-veil-wave, sheet-like structure with a high surface area of ∼1225 m2 g−1 and a high porosity. The graphene-nanosheet electrode shows a specific capacitance of 115 F g−1 at 0.5 mA cm−2 and a high energy density of 36.8 W h kg−1 at a power density of 323 W kg−1, with an excellent cyclic stability of 88% over 2000 cycles. The observed good electrochemical energy-storage performance of the biomaterial-derived graphene-nanosheet electrode is due to the synergistic effect of the intrinsically large electrochemically active surface area, an enhanced ion diffusion, and an improved electrical conductivity.
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