Issue 11, 1991

High-temperature oxidation of ethanol. Part 1.—Ignition delays in shock waves

Abstract

The ignition characteristics of ethanol–oxygen mixtures have been studied behind reflected shock waves from 1080 to 1660 K, in the pressure range 1.8–4.6 bar and with equivalence ratios, ϕ, varying from 0.25 to 2, through measurements of the ignition delay times associated with pressure rise, τp, or light emission, τCO–O and τOH. Multiple regression analysis was applied to all the measured ignition delay times, τ in seconds, the reactant concentrations in mol cm–3, and the corresponding temperatures in K, yielding the global relations: τOH= 10–12.7 exp (+ 14780//T)[C2H5OH]–0.415[O2]–0.785[Ar]+0.648, τCO – O= 10–14.0 exp (+ 15550//T)[C2H5OH]–0.315[O2]–0.780[Ar]+0.259, τP= 10–14.0 exp (+ 16960//T)[C2H5OH]–0.130[O2]–0.784[Ar]+0.140

The regression analysis of variance indicated that the fitted equations are good predictors of the data in each case and regression of τP on τCO–O showed that they are experimentally indistinguishable.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans., 1991,87, 1691-1696

High-temperature oxidation of ethanol. Part 1.—Ignition delays in shock waves

M. P. Dunphy and J. M. Simmie, J. Chem. Soc., Faraday Trans., 1991, 87, 1691 DOI: 10.1039/FT9918701691

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