Issue 0, 1974
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

The phosphorus trichloride–oxigen–olefin reaction: scope and mechanism

Clive B. C. Boyce,   Shirley B. Webb  and  Lawrence Phillips  

Abstract

The principal products of the reaction of phosphorus trichloride and oxygen with a variety of olefins are the corresponding 2-chloroethyl phosphorodichloridate and 2-chloroethylphosphonic dichloride. A linear relationship between Σσpara(Hammett) values for the olefinic substituents and the molar ratios of phosphoric and phosphonic dichlorides is discussed in terms of a free-radical scheme that accounts for all the products.

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Article information

DOI
https://doi.org/10.1039/P19740001650
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 1650-1658

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The phosphorus trichloride–oxigen–olefin reaction: scope and mechanism

C. B. C. Boyce, S. B. Webb and L. Phillips, J. Chem. Soc., Perkin Trans. 1, 1974, 1650 DOI: 10.1039/P19740001650

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