Issue 10, 1997
From the journal:

Chemical Communications

A modular approach to ligands for asymmetric π-allyl palladium catalysed additions

Scott R. Gilbertson  and  Cheng-Wei T. Chang  

Abstract

A route to phosphinodihydrooxazoles is reported, which is used to synthesize ten new ligands whose ability to asymmetrically catalyse the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate is investigated; the best gave a palladium complex which catalyses the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate in 99% yield and 97% ee.

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Article information

DOI
https://doi.org/10.1039/A607200C
Article type
Paper

Chem. Commun., 1997, 975-976

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A modular approach to ligands for asymmetric π-allyl palladium catalysed additions

S. R. Gilbertson and C. T. Chang, Chem. Commun., 1997, 975 DOI: 10.1039/A607200C

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