Issue 1, 2001
From the journal:

New Journal of Chemistry

Design of meso-structured titanium oxo based hybrid organic–inorganic networks

Galo J. de A. A. Soler-Illia,a   Emmanuel Scolan,a   Audrey Louis,a   Pierre-Antoine Albouyb  and  Clément Sanchez*a  

* Corresponding authors

a Chimie de la Matière Condensée, UMR CNRS 7574, Uniersité Pierre et Marie Curie 4, place Jussieu, France
E-mail: clems@ccr.jussieu.fr

b Laboratoire de Physique des Solides, Uniersité Paris-Sud, Orsay Cedex, France

Abstract

Titanium oxo clusters or nanosized Ti–O particles with hydrophobic or hydrophilic character can be obtained by varying the sol–gel synthesis conditions. These species are potentially interesting nano-building blocks (NBB) in the design of textured materials. The reactivity of well-defined hydrophobic NBB towards different nucleophiles has been characterised and discussed, in order to understand the processes taking place in the formation of meso-organised hybrids. Subsequently, different synthesis conditions were used to generate textured titania-based hybrid phases, using PEO-based surfactants as templating agents. The tuning of the interactions between the template and the different kinds of nano-building blocks allow worm-like and hexagonal titania-based hybrid phases to be reproducibly obtained.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B006139P
Article type
Paper
Submitted
27 Jul 2000
Accepted
13 Sep 2000
First published
07 Nov 2000

New J. Chem., 2001,25, 156-165

Permissions

Request permissions

Design of meso-structured titanium oxo based hybrid organic–inorganic networks

G. J. D. A. A. Soler-Illia, E. Scolan, A. Louis, P. Albouy and C. Sanchez, New J. Chem., 2001, 25, 156 DOI: 10.1039/B006139P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements