Issue 10, 2002

Low-temperature and catalyst-free synthesis of well-aligned ZnO nanorods on Si (100)

Abstract

Well-aligned ZnO nanorods have been grown on Si (100) substrates using a simple, catalyst-free CVD method at low temperatures. Structural analyses show that the nanorods grown on Si (100) are preferentially oriented in the c-axis direction. An amorphous SiOx layer in the interface of ZnO nanorods and Si (100) is observed from the HRTEM and EELS images. The well-aligned ZnO nanorods exhibit a strong PL emission of 380 nm at room temperature. A negligible green band emission in the PL spectra indicates that there is a very low concentration of oxygen vacancies in the highly oriented ZnO nanorods. Diameter control of the well-aligned and high-quality ZnO nanorods on Si (100) substrates is achievable by varying the growth conditions.

Graphical abstract: Low-temperature and catalyst-free synthesis of well-aligned ZnO nanorods on Si (100)

Article information

Article type
Paper
Submitted
22 Apr 2002
Accepted
24 Jun 2002
First published
09 Aug 2002

J. Mater. Chem., 2002,12, 3125-3129

Low-temperature and catalyst-free synthesis of well-aligned ZnO nanorods on Si (100)

S. Liu and J. Wu, J. Mater. Chem., 2002, 12, 3125 DOI: 10.1039/B203871D

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