Issue 1, 2003
From the journal:

New Journal of Chemistry

Nanocrystallised titania and zirconia mesoporous thin films exhibiting enhanced thermal stability

Eduardo L. Crepaldi,a   Galo J. de A. A. Soler-Illia,a   David Grossoa  and  Clément Sanchez*a  

* Corresponding authors

a Laboratoire de Chimie de la Matière Condensée, Université Pierre et Marie Curie (Paris VI) - CNRS, 4, place Jussieu (T54-E5), Paris cedex 05, France
E-mail: clems@ccr.jussieu.fr
Fax: +33 1 44 27 47 69
Tel: +33 1 44 27 33 65

Abstract

Tuned chemical conditions complemented with a set of treatments have been developed to enhance the thermal stability of transition metal oxide mesoporous thin films (up to 500 °C for TiO2 and 450 °C for ZrO2), allowing the formation of crack-free coatings presenting excellent optical quality (transmittance higher than 85% in the visible region), tailored thickness (from 50 to 700 nm), a highly organised cubic (Im3m space group for TiO2) or 2D-hexagonal (P6m space group for ZrO2) mesostructure, high surface area (140–200 m2 g−1), controlled and narrowly distributed mesopore size (25–80 Å), and a nanocrystalline inorganic framework (anatase or tetragonal zirconia).

Graphical abstract: Nanocrystallised titania and zirconia mesoporous thin films exhibiting enhanced thermal stability

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Article information

DOI
https://doi.org/10.1039/B205497N
Article type
Letter
Submitted
04 Jun 2002
Accepted
09 Sep 2002
First published
18 Oct 2002

New J. Chem., 2003,27, 9-13

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Nanocrystallised titania and zirconia mesoporous thin films exhibiting enhanced thermal stability

E. L. Crepaldi, G. J. D. A. A. Soler-Illia, D. Grosso and C. Sanchez, New J. Chem., 2003, 27, 9 DOI: 10.1039/B205497N

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