Issue 2, 2003
From the journal:

Physical Chemistry Chemical Physics

New types of polycarbonyls of Co+ formed after interaction of CO with Co–ZSM-5: An FTIR spectroscopic study

K. Hadjiivanov,*a   B. Tsyntsarski,a   Tz. Venkov,a   M. Daturi,b   J. Sausseyb  and  J.-C. Lavalleyb  

* Corresponding authors

a Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria
E-mail: kih@svr.igic.bas.bg
Fax: +003592 705024
Tel: +003592 9793598

b Laboratoire Catalyse et Spectrochimie, CNRS-ISMRA, Université de Caen, 6, bd Maréchal Juin, Caen Cedex, France

Abstract

Reduction of Co–ZSM-5 with CO results in the creation of Co+ cations forming Co+(CO)2 species (bands at 2112 and 2042 cm−1) which are converted into Co+(CO)3 tricarbonyls (2137, 2089 and 2079 cm−1) in the presence of CO.

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Article information

DOI
https://doi.org/10.1039/B210476H
Article type
Communication
Submitted
25 Oct 2002
Accepted
28 Nov 2002
First published
06 Dec 2002

Phys. Chem. Chem. Phys., 2003,5, 243-245

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New types of polycarbonyls of Co+ formed after interaction of CO with Co–ZSM-5: An FTIR spectroscopic study

K. Hadjiivanov, B. Tsyntsarski, Tz. Venkov, M. Daturi, J. Saussey and J.-C. Lavalley, Phys. Chem. Chem. Phys., 2003, 5, 243 DOI: 10.1039/B210476H

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