Issue 1, 2005
From the journal:

New Journal of Chemistry

Amine adducts of titanium tetraalkoxides

Helmut Frica  and  Ulrich Schubert*a  

* Corresponding authors

a Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9, Wien, Austria
E-mail: uschuber@mail.zserv.tuwien.ac.at

Abstract

The crystalline compounds Ti2(OiPr)8(NH2Pr)2, Ti2(OiPr)6(OEt)2[NH2(CH2)3Si(OiPr)3]2 and Ti2(OiPr)8[NH2(CH2)6NH2] were obtained by reaction of Ti(OiPr)4 with the corresponding amines. The molecular structures of the amine adducts are centrosymmetric dimers in which the titanium atoms are bridged by two OR groups. The amines are coordinated axially to the Ti2(µ-OR)2 ring and hydrogen-bonded to a neighboring propoxy ligand. In the case of the 1,6-diaminohexane derivative, this results in coordination polymers where the Ti2(OiPr)8 units are interconnected by the diamine.

Graphical abstract: Amine adducts of titanium tetraalkoxides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B411688G
Article type
Paper
Submitted
29 Jul 2004
Accepted
21 Sep 2004
First published
08 Dec 2004

New J. Chem., 2005,29, 232-236

Permissions

Request permissions

Amine adducts of titanium tetraalkoxides

H. Fric and U. Schubert, New J. Chem., 2005, 29, 232 DOI: 10.1039/B411688G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements