Issue 45, 2006

Synthesis and characterization of orthorhombic, 2d-centered rectangular and lamellar iron oxide doped silica films

Abstract

Iron oxide doped silica films and powders with highly ordered mesostructures of extraordinary temperature stability (up to 1000 °C) and iron loading of up to 6 atom% were produced by the use of novel iron alkoxide-coordinated surfactants. Wormhole-like, 2d-centered rectangular, orthorhombic and lamellar mesostructures were obtained by variation of the molar ratios of the metal–surfactant complexes. The influence of a subsequent heat treatment was studied by GI-SAXS, TEM, XRD, and nitrogen sorption techniques. The molecular composition of the films was studied by XPS and EXAFS.

Graphical abstract: Synthesis and characterization of orthorhombic, 2d-centered rectangular and lamellar iron oxide doped silica films

Article information

Article type
Paper
Submitted
05 May 2006
Accepted
17 Aug 2006
First published
26 Sep 2006

J. Mater. Chem., 2006,16, 4443-4453

Synthesis and characterization of orthorhombic, 2d-centered rectangular and lamellar iron oxide doped silica films

R. Supplit, N. Hüsing, H. Bertagnolli, M. Bauer, V. Kessler, G. A. Seisenbaeva, S. Bernstorff and S. Gross, J. Mater. Chem., 2006, 16, 4443 DOI: 10.1039/B606386A

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