Issue 26, 2009
From the journal:

Chemical Communications

Cooperativity in multiply H-bonded complexes†

Christopher A. Hunter,*a   Ndidi Ihekwaba,a   Maria Cristina Misuraca,a   Maria Dolores Segarra-Maseta  and  Simon M. Turegaa  

* Corresponding authors

a Department of Chemistry, University of Sheffield, Sheffield, UK
E-mail: c.hunter@shef.ac.uk
Fax: +44 (0)114 2229346
Tel: +44 (0)114 2229476

Abstract

The free energy of complexation of supramolecular complexes containing phenol–carbamateH-bonds is an additive function of the number of H-bonds, with a constant increment of 6 kJ mol−1 per interaction in carbon tetrachloride.

Graphical abstract: Cooperativity in multiply H-bonded complexes

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Article information

DOI
https://doi.org/10.1039/B908010D
Article type
Communication
Submitted
21 Apr 2009
Accepted
20 May 2009
First published
02 Jun 2009

Chem. Commun., 2009, 3964-3966

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Cooperativity in multiply H-bonded complexes

C. A. Hunter, N. Ihekwaba, M. C. Misuraca, M. D. Segarra-Maset and S. M. Turega, Chem. Commun., 2009, 3964 DOI: 10.1039/B908010D

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