The geometrical structures, relative stabilities, and electronic properties of small bare gold clusters Au^λ_n and bimetallic complexes of bare metal clusters with one copper atom Au_n−1Cu^λ (charge λ = 0, +1, −1; 2 ≤ n ≤ 9) have been systematically investigated by means of first-principles density functional calculations at the B3LYP level. The results show that the most stable isomers have a planar structure and resemble pure gold clusters in shape, and no three-dimensional isomers were obtained for neutral and anionic doped gold clusters. However, the geometries of Au_n−1Cu⁺ are found to undergo a structural change from two dimensional to three dimensional when the cluster contains 7 atoms. The calculated dissociation energy and second difference energy as a function of the cluster size exhibit a pronounced even–odd alternation phenomenon. Ionization potentials and electron detachment energies (both vertical and adiabatic) of Au^λ_nand Au_n−1Cu^λ clusters are discussed and compared with available experimental results. A good agreement between experimental and theoretical results suggests good prediction of the lowest energy structures for all clusters calculated in the present study.