Issue 10, 2010
From the journal:

Chemical Communications

Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

Kathrin Junge,a   Bianca Wendt,a   Nadim Shaikha  and  Matthias Beller*a  

* Corresponding authors

a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
E-mail: matthias.beller@catalysis.de
Fax: +49-381-1281-51113
Tel: +49-381-1281-113

Abstract

The iron-catalyzed reduction of aromatic nitro compounds to the corresponding anilines applying organosilanes is reported. In the presence of FeX2–R3P catalysts a series of nitroarenes is selectively reduced tolerating a wide range of functional groups.

Graphical abstract: Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

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Article information

DOI
https://doi.org/10.1039/B924228G
Article type
Communication
Submitted
18 Nov 2009
Accepted
22 Dec 2009
First published
13 Jan 2010

Chem. Commun., 2010,46, 1769-1771

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Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

K. Junge, B. Wendt, N. Shaikh and M. Beller, Chem. Commun., 2010, 46, 1769 DOI: 10.1039/B924228G

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