Issue 42, 2010

Designing late-transition metal catalysts for olefininsertionpolymerization and copolymerization

Abstract

The innovation of polyolefin with unique architecture, composition and topology continues to inspire polymer chemists. An exciting recent direction in the polyolefin field is the design of new catalysts based on late-transition metals. In this review, we highlight recent developments in rationally designing late-transition metal catalysts for olefin polymerization. The examples described in this review showcase the power of the design of well-defined late-metal catalysts for tailored polyolefin synthesis, which may usher in a new era in the polymer industry.

Graphical abstract: Designing late-transition metal catalysts for olefin insertion polymerization and copolymerization

Article information

Article type
Feature Article
Submitted
22 May 2010
Accepted
12 Aug 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7879-7893

Designing late-transition metal catalysts for olefin insertion polymerization and copolymerization

D. H. Camacho and Z. Guan, Chem. Commun., 2010, 46, 7879 DOI: 10.1039/C0CC01535K

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