Issue 10, 2010
From the journal:

Polymer Chemistry

Highly selective bisphenol A—imprinted polymers prepared by atom transfer radical polymerization†

Shogo Sasaki,a   Tooru Ooyaa  and  Toshifumi Takeuchi*a  

* Corresponding authors

a Graduate School of Engineering, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan
E-mail: takeuchi@gold.kobe-u.ac.jp
Fax: +81788036158
Tel: +81788036158

Abstract

Polymers molecularly imprinted toward bisphenol A (BPA-MIPs) were prepared by reverse atom transfer radical polymerization (reverse ATRP). For covalent bond-based BPA imprinting, a new template molecule, BPA di(4-vinyl benzoate), was synthesized and co-polymerized with divinylbenzene and styrene. Compared with conventional radical polymerization-based BPA-MIPs, the selectivities of the ATRP-based BPA-MIPs appear to be enhanced, suggesting that reverse ATRP could provide homogeneously cross-linked polymers and elaborate BPA recognition cavities in MIPs with size- and shape-selectivity.

Graphical abstract: Highly selective bisphenol A—imprinted polymers prepared by atom transfer radical polymerization

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Article information

DOI
https://doi.org/10.1039/C0PY00140F
Article type
Paper
Submitted
03 May 2010
Accepted
31 Jul 2010
First published
07 Sep 2010

Polym. Chem., 2010,1, 1684-1688

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Highly selective bisphenol A—imprinted polymers prepared by atom transfer radical polymerization

S. Sasaki, T. Ooya and T. Takeuchi, Polym. Chem., 2010, 1, 1684 DOI: 10.1039/C0PY00140F

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