Issue 44, 2011

Application of a chiral metal–organic framework in enantioselective separation

Abstract

A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal–organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.

Graphical abstract: Application of a chiral metal–organic framework in enantioselective separation

Supplementary files

Article information

Article type
Communication
Submitted
08 Aug 2011
Accepted
16 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2011,47, 12089-12091

Application of a chiral metal–organic framework in enantioselective separation

M. Padmanaban, P. Müller, C. Lieder, K. Gedrich, R. Grünker, V. Bon, I. Senkovska, S. Baumgärtner, S. Opelt, S. Paasch, E. Brunner, F. Glorius, E. Klemm and S. Kaskel, Chem. Commun., 2011, 47, 12089 DOI: 10.1039/C1CC14893A

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