Issue 35, 2011

Mechanistic analysis of trans C–N reductive elimination from a square-planar macrocyclic aryl-copper(iii) complex

Abstract

A net trans C–N reductive elimination reaction is observed from a macrocyclic aryl-CuIII complex, and a mechanistic study of this reaction indicates that coordinating ligands play a role in mediating this unusual transformation.

Graphical abstract: Mechanistic analysis of trans C–N reductive elimination from a square-planar macrocyclic aryl-copper(iii) complex

Supplementary files

Article information

Article type
Paper
Submitted
18 Mar 2011
Accepted
06 Apr 2011
First published
05 May 2011

Dalton Trans., 2011,40, 8959-8963

Mechanistic analysis of trans C–N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex

L. M. Huffman and S. S. Stahl, Dalton Trans., 2011, 40, 8959 DOI: 10.1039/C1DT10463B

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