Issue 44, 2011
From the journal:

Dalton Transactions

Chemoselective oxidation of primary alcohols catalysed by Ce(iii)-complex intercalated LDH using molecular oxygen at room temperature†

Sudarshan Singha,a   Mitarani Sahooa  and  K. M. Parida*a  

* Corresponding authors

a Colloids and Materials Chemistry Department, Institute of Minerals & Materials Technology, Bhubaneswar, Orissa, India
E-mail: paridakulamani@yahoo.com
Fax: 91674-2581637

Abstract

Herein we describe the preparation of an efficient heterogeneous catalyst consisting of an anionic Ce(III)-complex immobilized Zn/Al-layered double hydroxide (LDH) and its use in the catalytic liquid phase oxidation of primary alcohols using molecular O2 at room temperature. Various primary alcohols could be transformed to their corresponding aldehydes in good to excellent yields using the set of optimal conditions. The heterogeneous catalytic system can also be recovered and reused for several cycles without a significant loss of catalytic activity.

Graphical abstract: Chemoselective oxidation of primary alcohols catalysed by Ce(iii)-complex intercalated LDH using molecular oxygen at room temperature

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Article information

DOI
https://doi.org/10.1039/C1DT11140J
Article type
Paper
Submitted
17 Jun 2011
Accepted
19 Aug 2011
First published
04 Oct 2011

Dalton Trans., 2011,40, 11838-11844

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Chemoselective oxidation of primary alcohols catalysed by Ce(III)-complex intercalated LDH using molecular oxygen at room temperature

S. Singha, M. Sahoo and K. M. Parida, Dalton Trans., 2011, 40, 11838 DOI: 10.1039/C1DT11140J

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