Issue 32, 2012

Carbon-nanoparticles encapsulated in hollow nickel oxides for supercapacitor application

Abstract

Monodisperse carbon nanoparticles encapsulated in hollow NiO nanostructures (C@NiO) have been successfully synthesized by calcination from a Ni(OH)2 covered carbon (C@Ni(OH)2) precursor. The as-prepared products at each stage were extensively characterized and carefully discussed. The electrochemical properties of the carbon encapsulated in hollow NiO nanostructures were investigated using cycling voltammetry and charge–discharge techniques. The specific capacitance of the obtained C@NiO electrode was about 988.7 F g−1 at a current density of 0.5 A g−1. It shows better performance than hollow NiO spheres obtained in oxygen atmosphere. Furthermore, the C@NiO electrode shows a good capacitive retention of ca. 90.7% after 1000 charge–discharge cycles.

Graphical abstract: Carbon-nanoparticles encapsulated in hollow nickel oxides for supercapacitor application

Supplementary files

Article information

Article type
Paper
Submitted
10 Apr 2012
Accepted
19 Jun 2012
First published
20 Jun 2012

J. Mater. Chem., 2012,22, 16376-16381

Carbon-nanoparticles encapsulated in hollow nickel oxides for supercapacitor application

L. Fan, L. Tang, H. Gong, Z. Yao and R. Guo, J. Mater. Chem., 2012, 22, 16376 DOI: 10.1039/C2JM32241B

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