The single crystal X-ray analysis of [Au9{P(p-C6H4OMe)3}8]-(BF4)3; has provided the first example of a cluster compound with a metal atom incorporated into the centre of a puckered ring of like metal atoms.
K. P. Hall, B. R. C. Theoblad, D. I. Gilmour, D. M. P. Mingos and A. J. Welch, J. Chem. Soc., Chem. Commun., 1982, 528 DOI: 10.1039/C39820000528
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