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Electron microscopy, electron diffraction, EXAFS, and ultracentrifuging data show that a new catalytically active cluster prepared by reduction of Pd(OAc)2 by H2 in the presence of L = 1,10-phenanthroline, or 2,2′-bipyridine, followed by O2 treatment, contains a close-packed metal nucleus (570 ± 30 Pd atoms) bearing 60 ± 3 co-ordinated L and 180 ± 10 OAc– in the outer sphere of the cluster.
M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, I. I. Moiseev, V. A. Likholobov, D. I. Kochubey, A. L. Chuvilin, V. I. Zaikovsky, K. I. Zamaraev and G. I. Timofeeva, J. Chem. Soc., Chem. Commun., 1985, 937 DOI: 10.1039/C39850000937
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